Acta Chimica Sinica ›› 1978, Vol. 36 ›› Issue (2): 89-106. Previous Articles     Next Articles

同系物分子结构与物理化学性能间的定量关系——Ⅲ.联苯链物与骈苯链物电子光谱中的同系线性规律

蒋明谦   

  1. 中国科学院化学研究所
  • 投稿日期:1977-08-16 发布日期:2013-06-03

A QUANTITATIVE RELATIONSHIP BETWEEN MOLECULAR STRUCTURES AND PHYSICOCHEMICAL PROPERTIES OF HOMOLOGOUS COMPOUNDS——Ⅲ.THE RULE OF HOMOLOGOUS LINEARITY FOR THE ELECTRONIC SPECTRA OF POLYPHENYLS AND CONDENSED AROMATIC COMPOUNDS

CHIANG MING-CHIEN   

  1. Institute of Chemistry, Academia Sinica
  • Received:1977-08-16 Published:2013-06-03

In this paper the rule of homologous linearity for electronic spectra, namely,v=a+b (1/α)2/N has been extended to the homologous series of P-polyphenyls and cats-and pori-condensed aromatic hydrocarbons.For genuine homologous of the latter type, namely, condensed aromatic compounds of the same general structural formula and also with the same number of aromatic sextets, all the absorption peaks in each band of their electronic spectra conform alike to the linearity rule.The correlations are very satisfactory in almost all the cases studied.Furthermore, the linearity of the homologous lines obtained in this work is shown to be superior in precision to that based on the transition energies (mm+1-mm)calculated by the Hueckel molecular orbital method.