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Acta Chimica Sinica ›› 1981, Vol. 39 ›› Issue (2): 113-119. Previous Articles     Next Articles

自由基分解反应活化能的快速估算

罗渝然   

  1. 中国科学技术大学近代化学系 合肥
  • 投稿日期:1979-03-22 发布日期:2013-06-03

EMPIRICAL ESTIMATION OF ACTIVATION ENERGY FOR FREE RADICAL DECOMPOSITION

Luo YU-RAN   

  1. Department of Modern Chemistry, China University of Science and Technology, Hefei
  • Received:1979-03-22 Published:2013-06-03

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For the decomposition reaction of free radicals
R'→R+M
the activation energy has been estimated simply by the following equation:
E=Edo-V (R)
where Edo is a constant which depends only on the type of the product molecules M,V (R) is the redeformation energy of the group R.