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Acta Chimica Sinica ›› 1982, Vol. 40 ›› Issue (1): 91-93. Previous Articles     Next Articles

1, 7-二酮的成环反应 Ⅲ. 1, 7-二苯庚二酮-1, 7的酮-环醇互变异构

高济宇, 陈伟兴, 蒋昆   

  1. 南京大学化学系
  • 投稿日期:1979-04-17 发布日期:2013-06-03
  • 通讯作者: 高济宇

THE RING FORMATION OF 1, 7-DIKETONES Ⅲ. KETO-CYCLOL INTERCONVERSION OF 1, 7-DIPHENYLHEPTANDIONE-1, 7

GAO JI-YU(KAO TSI-YU), CHEN WEI-XING, JIANG KUN   

  1. Department of Chemistry, Nanjing University
  • Received:1979-04-17 Published:2013-06-03

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On treatment with sodium ethylate 1,7-diphenylheptandione-1,7 (1b) was converted into a mixture of 1-phenyl-2-benzoylcydohexanol (4b),2-phenyl-3-benzoyloydohexene (8b)and 1-phenyl-2-benzoyloyolohexene (2b).When treated with sodium ethylate, 4b was converted into 8b.