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Acta Chimica Sinica ›› 1982, Vol. 40 ›› Issue (4): 289-294.     Next Articles

镧系(Nd3+, Ho3+, Er3+)-1-苯基-3-甲基-4-苯甲酰基吡唑酮-5-8-羟基喹啉三元络合物的制备及超灵敏跃迁现象的研究

康敬万, 栾树森, 白光弼   

  1. 西北师范学院化学系 兰州
  • 投稿日期:1981-01-05 发布日期:2013-06-03
  • 通讯作者: 白光弼

A STUDY ON PREPARATION AND HYPERSENSITIVE TRANSITION PHENOMENON OF THE LANTHANIDES (Nd3+, Ho3+, Er3+)—1-PHENYL-3-METHYL-4-BENZOYL-PYRAZOLONE-5—8-HYDROXYQUINOLINE TERNARY COMPLEXES

KANG JING-WAN, LUAN SHU-SEN, BAI GUANG-BI   

  1. Department of Chemistry, Northwestern Normal College, Lanzhou
  • Received:1981-01-05 Published:2013-06-03

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The lanthanides (Nd3+,Ho3+.,Er3+) complexes with 1-phenyl-3-methyl-4-ben-zoyl-pyrazolone-5 (Hpmbp) and 8-hydroxyquinoline (Ox) in ethanolic solution have been studied by spectrophotometry.The ethanolic solution spectra of Ln3+ (Nd,Ho,Er) nitrates,β-diketonate (Hpmbp) chelates and Ln3+-Hpmbp-Ox ternary complexes show the change of absorption bands of hypersensitive transition and the corresponding incroaso of absorbance.Using the methods of continuous-variation and equilibriumshift,wo havo shown that in the ternary complexes formed,the ratio of components is Ln3+:Hpmbp:Ox-1:3:2.