Acta Chimica Sinica ›› 1982, Vol. 40 ›› Issue (9): 790-796. Previous Articles     Next Articles

巩县风化煤黄腐酸在有机溶剂中溶解机理的研究

王天立, 陈荣峰   

  1. 河南化学研究所 郑州
  • 投稿日期:1981-02-02 发布日期:2013-06-03
  • 通讯作者: 王天立

INVESTIGATION ON THE MECHANISM OF DISSOLUTION OF COAL FULVIC ACID IN ORGANIC SOLVENTS

WANG TIAN-LI, CHEN RONG-FENG   

  1. Henan Research Institute of Chemistry, Zhengzhou
  • Received:1981-02-02 Published:2013-06-03

A series of solvents is suggested for studying the dissolution mechanism of the fulvic acid from Gongxian weathered coal.It has been found that the solubilities of the fulvic acid in different organic solvents depend mainly on the solvent's parameter δa,which represents the hydrogen bonding ability of the solvem i.e.the solubility of the coal fulvie acid increases with the δa value of the solvent.These fractions separated by various solvents have been ehararcterized by elemental and functional group analyses.1R.a.nd 13C NMR.The results show that the regular changes of aromatioity and quinonoie contents in different fractions a.re in agreement with the proposed dissolution mechanism in which tho formation of hydrogen bonding is regarded as the leading factor in di}sulution.