The chlorination product of 2-hexadecyloxybenzoyl acetyl-(2'- chloro-5'-sulfonylanilino)-aniline by sulfuryl chloride

Acta Chimica Sinica ›› 1983, Vol. 41 ›› Issue (9): 857-859. Previous Articles Next Articles

Original Articles

成黄成色剂2-十六烷氧基苯甲酰乙酰基-(2'-氯-5'-苯胺磺酰基)苯胺氯化产物的鉴识

张斌;赵玉芬;刘丽珍;徐萌山;陈德俊

中国科学院化学研究所

发布日期:1983-09-15

The chlorination product of 2-hexadecyloxybenzoyl acetyl-(2'- chloro-5'-sulfonylanilino)-aniline by sulfuryl chloride

ZHANG BIN;ZHAO YUFEN;LIU LIZHEN;XU MENGSHAN;CHEN DEJUN

Published:1983-09-15

Abstract

Much work has been recorded in the literature concerning chlorination of photographic couplers. However, no detailed report can be found with the coupler of the structure 1. In this paper, the chlorination of 1 using SO2Cl2 in CHCl3 was shown to give the chlorination product 2. UV, IR, 1H NMR and MS of the chlorination product are compared with that of 1, and with those reported in the literature for benzoylacetanilide. Thermolysis of 2 gives a liquid fraction, HPLC shows one peak, which was identifield by 1H NMR and MS to be o-CH3COC6H4OCH2CHClC14H29. Elemental analyses as well as MS of its 2, 4-dinitrophenylhydrazone agree well with the structure assigned.

Key words: C16 COMPOUNDS, COLOR COUPLERS, YELLOW COLOR COUPLER, BENZENECARBOXYLIC ACID P, CHLORINATION REACTION, ANILINE, ACETYL GROUP

CLC Number:

O621
TQ57

Cite this article

ZHANG BIN;ZHAO YUFEN;LIU LIZHEN;XU MENGSHAN;CHEN DEJUN. The chlorination product of 2-hexadecyloxybenzoyl acetyl-(2'- chloro-5'-sulfonylanilino)-aniline by sulfuryl chloride[J]. Acta Chimica Sinica, 1983, 41(9): 857-859.

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成黄成色剂2-十六烷氧基苯甲酰乙酰基-(2'-氯-5'-苯胺磺酰基)苯胺氯化产物的鉴识

The chlorination product of 2-hexadecyloxybenzoyl acetyl-(2'- chloro-5'-sulfonylanilino)-aniline by sulfuryl chloride

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