Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (12): 1217-1218. Previous Articles    

Original Articles

十五碳内酯的简易合成法

郭茂道;陈煜强;毕明珠;沈美萍   

  1. 轻工业部香料工业科学研究所
  • 发布日期:1987-12-15

Facile synthesis of cyclopentadecanolide

GUO MEODAO;CHEN YUQIANG;BI MINGZHU;SHEN MEIPING   

  • Published:1987-12-15

The kernel oil from the seeds of Malania Oleifera on saponification gave tetracos-15-enoic acid which is converted to w-hydroxypentadecanoic acid (I) in 75% yield through ozonization and borohydride reduction Polycondensation of I and depolymn. using K2CO3 as catalyst and PEG-4000 as phase transfer catalyst gave 91% yield of cyclopentadecanolide.

Key words: LACTONES, MACROCYCLIC COMPOUNDS, SYNTHETIC PERFUMES, C15 COMPOUNDS

CLC Number: