Reaction of polyfluorocarbons II: Reaction of fluorochloroalkenes with aluminum chloride

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (2): 201-203. Previous Articles Next Articles

Original Articles

多氟代烃类的反应II: 氟氯烯烃与三氯化铝的反应

胡昌明;陆亨尧

中国科学院上海有机化学研究所

发布日期:1987-02-15

Reaction of polyfluorocarbons II: Reaction of fluorochloroalkenes with aluminum chloride

HU CHANGMING;LU HENGYAO

Published:1987-02-15

Abstract

Both CCl2FCF2CF:CF2 (I) and CCl2FCF:CFCF3 reacted with AlCl3 to yield rearrangement product CCl2:CFCF2CF3 (II). Such results supported intramol rearrangement mechanism from I to II. Under drastic condition II reacted further with AlCl3 to yield CCl2:CFCCl2CF3, CCl2:CClCCl2CF3, CCl2:CClCCl2CClF2, CCl2:CClCCl2CFCl2 and CCl2:CClCCl2CCl3. The effects of reaction conditions on the yields of products was discussed.

Key words: ALUMINIUM CHLORIDE, CHLOROHYDROCARBON, CHLOROHYDROCARBON, REARRANGEMENT REACTION, ALKENE P, FLUOROHYDROCARBON, FLUOROHYDROCARBON, POTASSIUM PERMANGANATE, PROPENE P, PROPENE P

CLC Number:

O621

Cite this article

HU CHANGMING;LU HENGYAO. Reaction of polyfluorocarbons II: Reaction of fluorochloroalkenes with aluminum chloride[J]. Acta Chimica Sinica, 1987, 45(2): 201-203.

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多氟代烃类的反应II: 氟氯烯烃与三氯化铝的反应

Reaction of polyfluorocarbons II: Reaction of fluorochloroalkenes with aluminum chloride

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