Synthesis and crystal structure of a new type of the mixed metal cluster (h^5-C5H5)(4Mo4Fe2(\m3-S)5(CO)5

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (2): 208-209. Previous Articles Next Articles

Original Articles

一种新型的混合金属原子簇化合物(η^5-C5H5)4Mo4Fe2-(μ3-S)5(CO)5的合成和晶体结构

黄锦顺;蔡钦荣;何美云;黄明生;卢嘉锡

中国科学院福建物质结构研究所

发布日期:1987-02-15

Synthesis and crystal structure of a new type of the mixed metal cluster (h^5-C5H5)(4Mo4Fe2(\m3-S)5(CO)5

HUANG JINSHUN;CAI QINGRONG;HE MEIYUN;HUANG MINGSHENG;LU JIAXI

Published:1987-02-15

Abstract

The title compound was prepared by reaction of (h5-C5H5)2Mo2(CO)6 and Fe3S2(CO)9 in PhMe and its crystal and mol. structures were studied by x-ray structure anal. The mol. is composed of a cubane-like [FeMo3S4] core and a trigonal pyramidal [MoFe2S] core linked through a shared Fe(1) atom.

Key words: CRYSTAL STRUCTURE DETERMINATION, IRON COMPLEX, CARBONYL COMPLEX, NITROGENASE, MOLYBDENUM COMPLEX, CLUSTER COMPOUND, SULFIDE COMPLEX, CONFIGURATION

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HUANG JINSHUN;CAI QINGRONG;HE MEIYUN;HUANG MINGSHENG;LU JIAXI. Synthesis and crystal structure of a new type of the mixed metal cluster (h^5-C5H5)(4Mo4Fe2(\m3-S)5(CO)5[J]. Acta Chimica Sinica, 1987, 45(2): 208-209.

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一种新型的混合金属原子簇化合物(η^5-C5H5)4Mo4Fe2-(μ3-S)5(CO)5的合成和晶体结构

Synthesis and crystal structure of a new type of the mixed metal cluster (h^5-C5H5)(4Mo4Fe2(\m3-S)5(CO)5

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