The reaction of tetrafluroethylene oligomers VII: Intramolecular rearrangement of polyfluoroalkylthioether and its kinetic studies

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (4): 370-373. Previous Articles Next Articles

Original Articles

四氟乙烯齐聚体的反应VII:多氟烷基硫醚的分子内重排及其动力学的研究

陈立佛;赵成学;王均环;曲延玲

中国科学院上海有机化学研究所

发布日期:1987-04-15

The reaction of tetrafluroethylene oligomers VII: Intramolecular rearrangement of polyfluoroalkylthioether and its kinetic studies

CHEN LIFU;ZHAO CHENGXUE;WANG JUNHUAN;QU YANLING

Published:1987-04-15

Abstract

Heating CF3C(C2F5)2C(:CF2)CF(CF3)SCH2Ph in CCl4 gave CF3C(C2F5)2C(CF2CH2Ph):CFCF3. The kinetics of rearrangement was examined by crossing reaction, solvent effects, the change of reactant concentration, and trapping experiment The reaction might occur via an intramol. nucleophilic. rearrangement process.

Key words: REACTION KINETICS, CONCENTRATION, SULFUR ETHER, REARRANGEMENT REACTION, ALKANE P, SOLVENT EFFECT, CROSSED IMMUNITY, TETRAFLUORO ETHYLENE, FLUOROHYDROCARBON, REACTION RATE

CLC Number:

O621.16

Cite this article

CHEN LIFU;ZHAO CHENGXUE;WANG JUNHUAN;QU YANLING. The reaction of tetrafluroethylene oligomers VII: Intramolecular rearrangement of polyfluoroalkylthioether and its kinetic studies[J]. Acta Chimica Sinica, 1987, 45(4): 370-373.

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四氟乙烯齐聚体的反应VII:多氟烷基硫醚的分子内重排及其动力学的研究

The reaction of tetrafluroethylene oligomers VII: Intramolecular rearrangement of polyfluoroalkylthioether and its kinetic studies

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