Study on the thermodynamic properties of adduct formation between bis-(O,O'-dioctyldithiophosphato)nickel(II) and the primary alkanol by GLC method

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (8): 740-745. Previous Articles Next Articles

Original Articles

气液色谱法研究双-(O,O'-二正辛基二硫代磷酸酯)合镍(II)与伯醇加合反应的热力学性质

徐正;俞运鹏;游效曾

南京大学配位化学研究所

发布日期:1988-08-15

Study on the thermodynamic properties of adduct formation between bis-(O,O'-dioctyldithiophosphato)nickel(II) and the primary alkanol by GLC method

XU ZHENG;YU YUNPENG;YOU XIAOZENG

Published:1988-08-15

Abstract

The gas-liq. chromatog. study on the thermodn. properties of adduct formation reactions between Ni[C8H17O)2PS2]2 and primary alkanols (C1-C4) is reported. The equilibrium constants of the reactions were determine at several temps. Thermodn. parameters were determine by graphic method.

Key words: THERMODYNAMIC PROPERTIES, MONOHYDRIC ALCOHOL, GAS LIQUID CHROMATOGRAPHY, EQUILIBRIUM CONSTANT, OCTANE P, PHOSPHORIC ACID ESTER, NICKEL COMPLEX, PHOSPHORODITHIOIC ACID P, ADDITIVE EFFECT

CLC Number:

O642
O658

Cite this article

XU ZHENG;YU YUNPENG;YOU XIAOZENG. Study on the thermodynamic properties of adduct formation between bis-(O,O'-dioctyldithiophosphato)nickel(II) and the primary alkanol by GLC method[J]. Acta Chimica Sinica, 1988, 46(8): 740-745.

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气液色谱法研究双-(O,O'-二正辛基二硫代磷酸酯)合镍(II)与伯醇加合反应的热力学性质

Study on the thermodynamic properties of adduct formation between bis-(O,O'-dioctyldithiophosphato)nickel(II) and the primary alkanol by GLC method

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