Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (12): 1174-1177. Previous Articles     Next Articles

Original Articles

2-甲基喹 淋与Cu(ClO~4)~2和Cu(BF~4)~2生成配合物的结构研究

白令君;李盛荣;王耕霖   

  1. 南开大学化学系
  • 发布日期:1989-12-15

The study of complexes of 2-methylquinoxaline with Cu(ClO~4)~2 and Cu(BF~4)~2

BAI LINGJUN;LI SHENGRONG;WANG GENGLIN   

  • Published:1989-12-15

Five coordination compounds of 2-methylquinoxaline with Cu(ClO4)2 or Cu(BF4)2 have been synthesized and characterized by elemental anal., elec. conductivity, IR, ESR and electronic spectra, TGA and temperature dependent (1.5-300 K) magnetic susceptibility measurements. The composition and configuration of these complexes have been proposed. A linear Cu(II)-O-Cu(II) bridged structure existed in 3 of the antiferromagnetic dimeric complexes.

Key words: INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, COPPER COMPLEX, THERMOGRAVIMETRY, ELECTRON SPIN RESONANCE, DINUCLEAR COMPLEX, CHLORATE, MAGNETIZATION, FLUOROBORATE, QUINOXALINE P

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