Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (2): 204-207. Previous Articles    

Original Articles

Schiff碱配合物的研究II: 一些Fe(III)配合物的磁性质与电化学行为

汪信;KOTUN, M.E.;FANNING, J.C   

  1. 华东工学院近代化学研究室;美国克莱姆森大学化学系
  • 发布日期:1990-02-15

Studies on schiff base complexes: II, magnetic and electrochemical behaviors of some iron (III)complexes

WANG XIN;KOTUN, M.E.;FANNING, J.C   

  • Published:1990-02-15

The magnetic and electrochem. properties of Fe(III) complexes Fe(salen)NO2, [Fe(salen)NO3]2, Fe(salen)(SCN), K[Fe(salen)(CN)2], [Fe(salen)]2O and [Fe(5-NO2 saldpt]2O, where salen = salicylidene-ethylenediamine and saldpt = salicylidene-propylenediamine, were studied. The NMR chem. shifts and the Moessbauer spectra parameters were determine experimental The oxidation- behavior was studied by cyclic voltammetry. The effects of m-oxo bridging on the structure and electrochem properties were studied.

Key words: IRON COMPLEX, NUCLEAR MAGNETIC RESONANCE, SCHIFF BASE, MAGNETISM, ELECTROCHEMISTRY

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