Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (4): 355-359. Previous Articles     Next Articles

Original Articles

若干"大乌型"Schiff碱配合物合成和性质的研究

罗勤慧;杨升;沈孟长;张正   

  1. 南京大学配位化学研究所;南京大学化学系
  • 发布日期:1990-04-15

A study on synthesis and properties of some "Big Bird" schiff base complexes

LUO QINHUI;YANG SHENG;SHEN MENGCHANG;ZHANG ZHENG   

  • Published:1990-04-15

M2L(OEt) (M = Cu, Ni, Pb, Cd; H3L = I) and Co(HL) were prepared I was prepared by condensation of 4-tert-butyl-2,6-diformylphenol and Me(CH2)5HNC(S)NHNH2. Each binuclear complex has an ethoxide bridging ligand. In the Co complex the phenolic O is protonated. Interaction of the Ni complex, which is paramagnetic, with pyridine was studied by NMR.

Key words: PHENOL P, CONDENSATION REACTION, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, COPPER COMPLEX, COBALT COMPLEX, NICKEL COMPLEX, SCHIFF BASE, ACYL GROUP, LEAD COMPLEX

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