Studies on the total synthesis of koumine-synthesis of 16-oxo-△ ^1^9-sarpagine skeleton

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (3): 290-296. Previous Articles Next Articles

Original Articles

钩吻素子的全合成研究-具有19-C, 20-C双键、16-C氧代的蛇根精架的合成

徐风;刘铸晋

中国科学院上海有机化学研究所

发布日期:1991-03-15

Studies on the total synthesis of koumine-synthesis of 16-oxo-△ ^1^9-sarpagine skeleton

XU FENG;LIU ZHUJIN

Published:1991-03-15

Abstract

The facile construction of a sarpagine ring system I was achieved via radical cyclization of II with Mn(III)/Cu(II).

Key words: C16 COMPOUNDS, CYCLIZATION, OXYGEN HETEROCYCLICS, C20 COMPOUNDS, C19 COMPOUNDS, KOUMINE, SARPAGINE ALKALOID, TOTAL SYNTHESIS, DOUBLE BONDS

CLC Number:

O627

Cite this article

XU FENG;LIU ZHUJIN. Studies on the total synthesis of koumine-synthesis of 16-oxo-△ ^1^9-sarpagine skeleton[J]. Acta Chimica Sinica, 1991, 49(3): 290-296.

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钩吻素子的全合成研究-具有19-C, 20-C双键、16-C氧代的蛇根精架的合成

Studies on the total synthesis of koumine-synthesis of 16-oxo-△ ^1^9-sarpagine skeleton

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