Reaction of allyl bromides with α,β-unsaturated aldehydes, ketones and quinones

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (8): 827-832. Previous Articles

Original Articles

金属锡作用下烯丙基溴与α,β-不饱和醛、酮和醌的反应

高翔;黄邦州;吴世晖

复旦大学化学系

发布日期:1991-08-15

Reaction of allyl bromides with α,β-unsaturated aldehydes, ketones and quinones

GAO XIANG;HUANG BANGZHOU;WU SHIHUI

Published:1991-08-15

Abstract

In the presence of metallic tin, allyl bromides react with a,b-unsatd. aldehydes and ketones regioselectively to give only 1,2-addn. products. Allylquinones were obtained by the reaction of 1,4-quinones with allyl bromides and metallic tin, followed by oxidation with ferric chloride.

Key words: TIN, BROMIDE, QUINONE, QUINONE, CARBONYL COMPOUNDS, ADDITION REACTION, KETONE, ALLYL GROUP, ALLYL GROUP, UNSATURATED COMPOUND

CLC Number:

O621

Cite this article

GAO XIANG;HUANG BANGZHOU;WU SHIHUI. Reaction of allyl bromides with α,β-unsaturated aldehydes, ketones and quinones[J]. Acta Chimica Sinica, 1991, 49(8): 827-832.

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金属锡作用下烯丙基溴与α,β-不饱和醛、酮和醌的反应

Reaction of allyl bromides with α,β-unsaturated aldehydes, ketones and quinones

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