Synthesis and crystallographic structure of substituted benzyl pentamethoxycarbonyl cyclopentadienes

Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (5): 434-438. Previous Articles Next Articles

Original Articles

取代苄基五甲氧羰基环戊二烯的合成和晶体结构

丘昌隆;祝英;苗果斌;桑冬梅

兰州大学化学系;兰州大学分析测试中心

发布日期:1992-05-15

Synthesis and crystallographic structure of substituted benzyl pentamethoxycarbonyl cyclopentadienes

QIU CHANGLONG;ZHU YING;MIAO GUOBIN;SANG DONGMEI

Published:1992-05-15

Abstract

Seven title compounds have been synthesized from the reaction of potassium pentamethoxycarbonylcyclopentadienide with substituted benzyl halides. All of these products have the carbon-carbon linkage to the cyclopentadiene ring. An x-ray diffraction investigation of 1-naphthylmethylpentamethoxycarbonylcyclopentadiene has unequivocally established its structure. The plane angle between the naphthalene ring and the cyclopentadiene ring is 68.19?

Key words: CRYSTAL STRUCTURE DETERMINATION, NAPHTHALENE P, CYCLOPENTADIENE P, BENZYL GROUP

CLC Number:

O621

Cite this article

QIU CHANGLONG;ZHU YING;MIAO GUOBIN;SANG DONGMEI. Synthesis and crystallographic structure of substituted benzyl pentamethoxycarbonyl cyclopentadienes[J]. Acta Chimica Sinica, 1992, 50(5): 434-438.

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取代苄基五甲氧羰基环戊二烯的合成和晶体结构

Synthesis and crystallographic structure of substituted benzyl pentamethoxycarbonyl cyclopentadienes

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