Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (10): 999-1004. Previous Articles     Next Articles

Original Articles

倒数示波计时电位法的研究: 新线路的研制及应用

朱俊杰;郑建斌;沈岚;高鸿;卜海之   

  1. 南京大学化学系;中国军事医学科学院药理毒理研究所
  • 发布日期:1993-10-15

Investigation on reciprocal oscillographic chronopotentiometry-preparation and application of new circuit

ZHU JUNJIE;ZHENG JIANBIN;SHEN LAN;GAO HONG;BU HAIZHI   

  • Published:1993-10-15

Reciprocal oscillog. chronopotentiometry is a new method which can overcome some weak points of classical oscillog. chronopotentiometry such as low sensitivity and poor linear relationship. A new circuit with feeding back current for obtaining reciprocal oscillogram has been designed. The main advantages of the circuit are its higher sensitivity and better linear relationship. In the experiment, the authors apply a new method to determine peak potential of some organic substances. If the authors connect the anodic stripping circuit with the reciprocal oscillog. chronopotentiometric instrument, min. detectable amount of metal ion can be down to 10-9 mol/L. Experimental results also show there is a better linear relationship between peak height and concentration of depolarizer in solution of 10-8 mol/L.9

Key words: DRUGS ANALYSIS, PYRIDINE P, TRACE ANALYSIS, OXIME

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