Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (8): 823-830. Previous Articles    

Original Articles

香芹酮的双重Michael反应和在天然产物手性合成中的应用

赵玉芬;赵荣宝;吴毓林   

  1. 中国科学院上海有机化学研究所;中国科学院生命有机化学国家重点实验室
  • 发布日期:1994-08-15

Double michael reaction of carvone and its utilization in chiral synthesis of natural products

ZHAO YUFEN;ZHAO RONGBAO;WU YULIN   

  • Published:1994-08-15

The double Michael reaction of carvone and Me methacrylate was described in detail. Its product, an optically active bicyclo[2.2.2]octane derivative I, is a useful intermediate for the chiral synthesis of natural products. In this respect an elemene derivative and an intermediate for the synthesis of (+)-curdione were synthesized.

Key words: ESTERS, CARVONE, BRIDGE COMPOUNDS, MICHAEL ADDITION REACTION, NATURAL PRODUCTS

CLC Number: