Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (9): 921-926. Previous Articles     Next Articles

Original Articles

三烃基锡β-2, 8, 9-三氧杂-5-氮杂-1-锗杂三环[3.3.3.0^1.5]十一碳烷基(β-取代)丙酸酯的研究

孙丽娟;刘华;谢庆兰   

  1. 南开大学元素有机化学重点实验室
  • 发布日期:1994-09-15

Trialkyltin β-2, 8, 9-trioxa-5-aza-1-germyltricyclo [3.3.3.0^1.5] undecanyl propionates

SUN LIJUAN;LIU HUA;XIE QINGLAN   

  • Published:1994-09-15

Fifteen new title compounds N(CH2CH2O)3GeCHR1CH2CO2SnR3 (R = Cy, Bu, Ph, R3 = Cy2Bu, CyBu2, R1 = H, Ph, p-CH3C6H4, p-ClC6H4) were synthesized and their structures identified by IR, 1H NMR, MS and elemental anal. The compounds may be five-coordinate when R = Bu, whereas the others are four-coordinate. From preliminary biol. tests these compounds have good acaricidal and herbicidal activities and display some fungicidal activity for plant diseases.

Key words: INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, ACARICIDES, HERBICIDES, ORGANO TIN COMPOUNDS, ORGANO GERMANIUM, OXAZOLIDINE

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