Acta Chimica Sinica ›› 1995, Vol. 53 ›› Issue (3): 305-309. Previous Articles     Next Articles

Original Articles

应用固-液相转移催1化方法合成肌醇磷酸脂

丁贻祥;周顺福;沈瑾   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1995-03-15

The synthesis of myo-inositol phosphates by S-L phase transfer catalytic method

DING YIXIANG;ZHOU SHUNFU;SHEN JIN   

  • Published:1995-03-15

Solid-liq. phase transfer catalysis has been used successfully in synthesis of myo-inositol phosphates. It efficiently improved the regioselectivity of alkylation of myo-inositol derivatives The Atherton-Todd reaction under solid-liq. PTC condition provided a novel phosphorylation method for myo-inositol derivatives The various phosphates of mono-, di-(included 1,2-di-), triol of myo-inositol have been conveniently prepared in good yield.

Key words: PHASE TRANSFER CATALYSIS, PROTON MAGNETIC RESONANCE SPECTROMETRY, PHOSPHORUS 31 MAGNETIC RESONANCE SPECTROMETRY, SELECTIVE PROTECTION

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