A mechanistic study on the electrochemical reduction of β- naphthyl sulfonic acid in acetonitrile solution at mercury electrode

Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (8): 783-789. Previous Articles Next Articles

Original Articles

乙腈中β-萘磺酸在汞电极上的电还原机理

黄树坤;陈德文;黄淑辉

湖南大学化学化工系;中国科学院化学研究所;清华大学化学工程系

发布日期:1996-08-15

A mechanistic study on the electrochemical reduction of β- naphthyl sulfonic acid in acetonitrile solution at mercury electrode

HUANG SHUKUN;CHEN DEWEN;HUANG SHUHUI

Published:1996-08-15

Abstract

The mechanism of electroreduction of α-naphthyl sulfonic acid at mercury electrode has been studied by means of cyclic voltammetry, electrochemical-ESR spectroscopy in-situ and SCFMO method (CNDO/2). The results showed that its electroreduction obeys ECE scheme involvingthe detachment of sulfonic acid group and the formation of β-naphthylradical. Some explanation for the electroreduction process has been put forward using molecular orbital theory.

Key words: CNDO APPROXIMATION, MOLECULAR ORBITAL THEORY, NAPHTHALENESULFONIC ACID, ELECTRON SPIN RESONANCE, MERCURY ELECTRODE, ACETONITRILE, CYCLOVOLTAMGRAPH

CLC Number:

O646

Cite this article

HUANG SHUKUN;CHEN DEWEN;HUANG SHUHUI. A mechanistic study on the electrochemical reduction of β- naphthyl sulfonic acid in acetonitrile solution at mercury electrode[J]. Acta Chimica Sinica, 1996, 54(8): 783-789.

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乙腈中β-萘磺酸在汞电极上的电还原机理

A mechanistic study on the electrochemical reduction of β- naphthyl sulfonic acid in acetonitrile solution at mercury electrode

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