Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (7): 644-648. Previous Articles     Next Articles

Original Articles

硝基苯与正十六烷二元溶液在临界区域的浊度

安学勤;蒋富国;陈传缨;周从山;方建;沈伟国   

  1. 兰州大学化学系
  • 发布日期:1998-07-15

Turbidity measurements of nitrobenzene in hexadecane in the critical region

AN XUEQIN;JIANG FUGUO;CHEN CHUANYING;ZHOU CONGSHAN;FANG JIAN;SHEN WEIGUO   

  • Published:1998-07-15

A series of turbidity measurements have been made for nitrobenzene in hexadecane in the critical region at various wavelengths and temperatures. Critical amplitudes ξ0, x0 and B corresponding to the correlation length, the susceptibility and the coexistence curve are related through R=ξ0[B^2/(4kBTcx0)]^1^/^3, where the value of R is 0.65-0.67. By using this relation the turbidity data have been fitted to Ornstein-Zernike equation to obtain critical exponents γ and ν, which are consistent with the theoretical values within experimental uncertainties. The experimental data have also been analyzed to determine critical amplitudes when the value of γ and ν are fixed at their theoretical values 1.241 and 0.63. The results have shown that ξ0 is 0.168nm (R=0.65) and 0.174nm (R=0.67), and x0 is 2.81×10^-^9m^3.J^-^1(R=0.65) and 2.85×10^-^9m^3.J^-^1 (R=0.67), respectively.

Key words: NITROBENZENE, TURBIDITY, LIGHT SCATTERING, CRITICAL REGION, DIOCTYL

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