Synthesis, spectroscopic and electrochemical  characterization of mixed [tetrakis(4-pyridyl) porphyrinato]  (2, 3, 9, 10, 16, 17, 23, 24- octaheptylphthalocyaninato)  yttrium sandwich complex

Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (12): 1285-1290. Next Articles

Original Articles

混杂[2, 3, 9, 10, 16, 17, 23, 24-八(庚基)酞菁][四(4-吡啶基)卟啉]合钇 (III)二层配合物的合成及其谱学和电化学性质

边永忠;于慧;姜建壮

山东大学化学系.济南(250100);山东大学环境工程系;北京大学稀土材料化学及应用国家重点实验室.北京

发布日期:1999-12-15

Synthesis, spectroscopic and electrochemical characterization of mixed [tetrakis(4-pyridyl) porphyrinato] (2, 3, 9, 10, 16, 17, 23, 24- octaheptylphthalocyaninato) yttrium sandwich complex

Bian Yongzhong;Yu Hui;Jiang Jianzhuang

Shandong Univ, Dept Chem.Jian(250100);.

Published:1999-12-15

Abstract

Mixed [tetrakis (4-pyridyl) porphyrinato] (2, 3, 9, 10, 16, 17, 23, 24-octaheptylphthalocyaninato) yttrium sandwich complex was obtained by tetramerization of phthalonitrile C~6H~2(C~7H~1~5)~2 on the template of monomeric porphyrinato yttrium Y(TPyP) acac in the presence of 1, 8-diazabicyclo [5.4.0] undec-7-ene (DBU). This compound was characterized by spectroscopic methods including UV-vis, near IR, IR and MS and CV (cyclovoltametry).

Key words: PORPHYRIN, PHTHALOCYANIN (=PHTHALOCYANINE), YTTRIUM COMPLEX, ULTRAVIOLET SPECTROPHOTOMETRY, INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, CYCLOVOLTAMGRAPH

CLC Number:

O646

Cite this article

Bian Yongzhong;Yu Hui;Jiang Jianzhuang. Synthesis, spectroscopic and electrochemical characterization of mixed [tetrakis(4-pyridyl) porphyrinato] (2, 3, 9, 10, 16, 17, 23, 24- octaheptylphthalocyaninato) yttrium sandwich complex[J]. Acta Chimica Sinica, 1999, 57(12): 1285-1290.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Minghui He, Ziqiu Ye, Guiqing Lin, Sheng Yin, Xinyi Huang, Xu Zhou, Ying Yin, Bo Gui, Cheng Wang. Research Progress of Porphyrin-Based Covalent Organic Frameworks in Photocatalysis^★ [J]. Acta Chimica Sinica, 2023, 81(7): 784-792.
[2]	Wanhong Li, Mingyue Yu, Lili Wang, Dehuang Zhu, Suhong Peng, Hui Wang, Haiyang Liu. Sovlent Influence on the Femtosecond Transient Absorption Spectra of Tetraphenylporphyrin Manganese(III) Chloride [J]. Acta Chimica Sinica, 2023, 81(4): 345-350.
[3]	Yuguang Sui, Jinrong Zhou, Pan Liao, Wenjie Liang, Hai Xu. A Gaint Donor-Acceptor Molecular Switch Compound: Synthesis and Properties [J]. Acta Chimica Sinica, 2022, 80(8): 1061-1065.
[4]	Chaofeng Wang, Guodong Zheng, Yue Wang, Huijia Song, Xiaoyi Chen, Ruixia Gao. Preparation of Controllable Non-covalent Functionalized Carbon Nanotubes with Metalloporphyrin-Sn Network and Application to Protein Adsorption [J]. Acta Chimica Sinica, 2022, 80(2): 126-132.
[5]	Yin Cen, Wang Zikuan, Liu Dan, Peng Zhantao, Song Huanjun, Zhu Hao, Chen Qiwei, Wu Kai. Adsorption and Self-assembly of meso-tetra(p-methoxyphenyl)-porphyrinatocobalt(II) on Coinage Metal Surfaces [J]. Acta Chimica Sinica, 2020, 78(7): 695-702.
[6]	Chen Zhiyao, Liu Jiewei, Cui Hao, Zhang Li, Su Chengyong. Applications of Porphyrin Metal-Organic Frameworks in CO₂ Capture and Conversion [J]. Acta Chim. Sinica, 2019, 77(3): 242-252.
[7]	Long Saran, Wan Yan, Xia Andong. Spectral Properties of Water-Soluble Conjugated Polymer PFP/DNA/Porphyrin Complex [J]. Acta Chim. Sinica, 2015, 73(7): 723-728.
[8]	Yang Hui, Liu Libing, Zhang Zhou, Xue Zheng, Li Yongjun, Wang Shu, Liu Huibiao. Constructing High Luminescent Inorganic/Organic Hybrid Nanoscale Molecular Pockets [J]. Acta Chim. Sinica, 2014, 72(12): 1218-1222.
[9]	Zhu Chun, Cao Zexing. Unique Metal Di-Porphyrin Dyes with Excellent Photoelectronic Properties for Solar Cells：Insight from Density Functional Calculations [J]. Acta Chimica Sinica, 2013, 71(11): 1527-1534.
[10]	Zhang Xianxia, Chen Canyu. Development of Study on Water-Soluble Porphyrins and Metalloporphyrins in DNA [J]. Acta Chimica Sinica, 2012, 70(24): 2475-2483.
[11]	LIU Jing-Zhou, MA Wang-Yang, LI Jun, YAO Gui-Ping, LUO Yun, ZHANG Feng-Xing, WANG Jun-Long. Preparation of TiO_{2 Photocatalyst Modified by meso-5,10,15,20- Tetrakis(2-thienyl) Metalloporphyrins and Their Photocatalytic Activities} [J]. Acta Chimica Sinica, 2011, 69(23): 2821-2826.
[12]	SUN Yuan-Yuan, LIAN Wen-Hui, WANG Jian-Cheng, WANG Bin-Bin, DAN Ning, YU Lian-Xiang, YU Miao, SHI Tong-Shun. Synthesis and Characterization of (E)-2-Butenedioyl Dichlorid Bridge-linked 10,15,20-Tri(p-chlorophenyl)porphyrin Dimer and Its Complexes [J]. Acta Chimica Sinica, 2011, 69(20): 2465-2470.
[13]	CHEN Ying-Jun, GAO Bao-Jiao, TIAN Peng, MA Yun-Xia. Studies on Synchronously Synthsizing and Immobilizing Porphyrins on Crosslinked Polystyrene Microspheres and High Efficient Catalytic Performance of Immobilized Metalloporphyrins in Oxidation [J]. Acta Chimica Sinica, 2011, 69(11): 1337-1346.
[14]	ZHANG Hui, ZHAO Hong-Bin, LU Xu-Jia, WANG Wu-Lin, CHANG Hui, WANG Yu-Fang. Water-soluble Sulfonate Sodium Phenyl Porphyrin and Its Metal Complexes Covalently and Non-covalently Modification Multi-Walled Carbon Nanotubes [J]. Acta Chimica Sinica, 2011, 69(03): 316-324.
[15]	ZHUANG Chang-Fu, SUN Yuan-Yuan, WANG Yun-Fang, SHI Jian-Hui, SHI Yu-Hua, SHI Tong-Shun. Preparation and Properties of 5-(4-Nicotinicaminophenyl)-10,15,20- triphenylporphyrin and Its Zn Complexes [J]. Acta Chimica Sinica, 2010, 68(22): 2319-2324.

混杂[2, 3, 9, 10, 16, 17, 23, 24-八(庚基)酞菁][四(4-吡啶基)卟啉]合钇 (III)二层配合物的合成及其谱学和电化学性质

Synthesis, spectroscopic and electrochemical characterization of mixed [tetrakis(4-pyridyl) porphyrinato] (2, 3, 9, 10, 16, 17, 23, 24- octaheptylphthalocyaninato) yttrium sandwich complex

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

混杂[2, 3, 9, 10, 16, 17, 23, 24-八(庚基)酞菁][四(4-吡啶 基)卟啉]合钇 (III)二层配合物的合成及其谱学和电化学性质

Synthesis, spectroscopic and electrochemical characterization of mixed [tetrakis(4-pyridyl) porphyrinato] (2, 3, 9, 10, 16, 17, 23, 24- octaheptylphthalocyaninato) yttrium sandwich complex

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

混杂[2, 3, 9, 10, 16, 17, 23, 24-八(庚基)酞菁][四(4-吡啶基)卟啉]合钇 (III)二层配合物的合成及其谱学和电化学性质