Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (2): 189-195. Previous Articles     Next Articles

Original Articles

二氯-二[2-四氧基-6-(2'-羟乙基亚胺基甲基)苯酚]合镉(II)的 合成、结构及激 光倍频效应

崔学桂;胡清萍;龚健   

  1. 山东大学化学学院.济南(250100)
  • 发布日期:1999-02-15

Synthesis, crystal structure and SHG effect of complex [Cd (CH3OC6H3OHCH=NC2H4OH)2Cl2].(1/2)C2H5OH

Cui Xuegui;Hu Qingping;Gong Jian   

  1. Shandong Univ., College of Chem.Jinan(250100)
  • Published:1999-02-15

The title complex [Cd(CH3OC6H3OHCH=NC2H4OH)2Cl2].(1/2)C2H5OH was synthesized and characterized by elemental analyses, IR as well as UV spectroscopy. Its structure was confirmed by single crystal X-ray diffraction. The complex crystal belongs to the monocline space group is Cc, with cell parameters: a=1.5475(3), b=1.1661(2), c=1.7295(3)nm, β=116.50(3)ⅲ, Z=4, final R=0.043 for 2261 unique reflections [I≥3σ (I)]. The structure was solved by direct method. The results indicate that each of the cadmium atoms was coordinated with four oxygen atoms (from two ligands respectively), and two chlorine anions to form a twisted octahedron. The complex has a high SHG efficiency.

Key words: CADMIUM COMPLEX, FREQUENCY EFFECT, LASER, NON LINEAR OPTIC CRYSTAL

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