Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (1): 39-42. Previous Articles     Next Articles

Original Articles

新型"分子合金"类Fe(II)配合物的合成和自旋转换性能

王红梅;刘欣;李立存;杨光明;廖代正;阎世平;姜宗慧   

  1. 南开大学化学系.天津(300071)
  • 发布日期:2000-01-15

The synthesis and spin transition behaviour of new molecular alloys Fe(II) complexes

Wang Hongmei;Liu Xin;Li Licun;Yang Guangming;Liao Daizheng;Yan Shiping;Jiang Zonghui   

  1. Nankai Univ, Dept Chem.Tianjin(300071)
  • Published:2000-01-15

Two new molecular alloys, the Fe[(Htrz)~9~/~4(NH~2trz)~3~/~4](BF~4) ~2.H~2O(1) and Fe[(Htrz)~3~/~2(NH~2trz)](BF~4).3H~2O(2), are synthesized and investigated by optical measurements (where Htrz stands for 4-H-1, 2, 4-triazole; NH~2trz for 4-NH~2-1, 2, 4-triazole) . Complexes 1 and 2 show spin transitions with hysteresis and thermochromism in the close vicinity of room temperature.

Key words: IRON COMPLEX, THERMOCHROMISM

CLC Number: