Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (11): 1365-1368. Previous Articles     Next Articles

Original Articles

单重态CCl~2与O~3反应的热力学及动力学性质研究

殷平;陈先阳;张建强;居冠之;李重德;忻新泉   

  1. 南京大学配位化学国家重点实验室.南京(210008);南京大学化学系.南京 (210008);上海交通大学应用化学系.上海(200030)
  • 发布日期:2000-11-15

Thermodynamic and kinetic studies on the reaction of singlet CCl~2 and O~3

Yin Ping;Chen Xianyang;Zhang Jianqiang;Ju Guanzhi;Li Zhongde;Xin Xinquan   

  1. Nanjing Univ, Coordinat Chem State Key Lab.Nanjing(210008);Nanjing Univ, Dept Chem.Nanjing(210008);Shanghai Jiao Tong Univ, Dept Appl Chem.Shanghai(200030)
  • Published:2000-11-15

The thermodynamic and kinetic studies have been carried out on the reaction of singlet CCl~2 and ozone O~3 at 200K~2000K, using statistic thermodynamic and Eyring transition state theory with Wigner correction on the basis of quantum chemistry. It is concluded that the reaction is thermodynamically favored at low temperatures but kinetically favored at high temperatures.

Key words: OZONE, SINGLET, TRANSITION STATE THEORY

CLC Number: