Catalytic effect of copper chloride on the toxic  emissions from combustion of polyvinyl chloride

Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (12): 1681-1684. Previous Articles

Original Articles

4氯化铜对聚氯乙烯燃烧产物的催化作用

王东利;徐晓白;郑明辉;Chung H. Chiu

中国科学院生态环境研究中心.北京(100085);Environmental Canada, Environmental Technology centre,;Ottawa, Ontario, Canada

发布日期:2000-12-15

Catalytic effect of copper chloride on the toxic emissions from combustion of polyvinyl chloride

Wang Dongli;Xu Xiaobai;Zheng Minghui;Chung H. Chiu

Eco Environm Sci Res Ctr, CAS.Beijing(100085)

Published:2000-12-15

Abstract

The effects of temperature and the amount of copper chloride on the types and yields of the toxic emissions from combustion of polyvinyl chloride were investigated. The results suggest that a large amount of polycyclic aromatic hydrocarbons (PAHs) are released from combustion of pure polyvinyl chloride, accompanied by a small amount of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs). Copper chloride can effectively enhance the formation of PCDD/Fs while possibly inhibit formation of PAHs. metal chlorides are possibly one of the main factors to enhance the PCDD/Fs formation from combustion of polyvinyl chloride.

Key words: COPPER CHLORIDE, POLYVINYL CHLORIDE, CATALYTIC REACTION, DIOXIN, POLYNUCLEAR ATOMATIC HYDROCARBON P, COMBUSTION PRODUCTS

CLC Number:

O643

Cite this article

Wang Dongli;Xu Xiaobai;Zheng Minghui;Chung H. Chiu. Catalytic effect of copper chloride on the toxic emissions from combustion of polyvinyl chloride[J]. Acta Chimica Sinica, 2000, 58(12): 1681-1684.

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4氯化铜对聚氯乙烯燃烧产物的催化作用

Catalytic effect of copper chloride on the toxic emissions from combustion of polyvinyl chloride

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