Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (2): 178-183. Previous Articles     Next Articles

Original Articles

铅基复合钙钛矿型弛豫铁电单晶的生长基元与生长机理: II.成 分、结构起伏与 同型生长基元的分异和组装

许桂生;罗豪Su;仲维卓;殷之文;刘克   

  1. 湘潭工学院;中国科学院上海硅酸盐研究所.上海(200050);中国科学院无机功 能材料开放实验室
  • 发布日期:2000-02-15

Growth units and growth mechanism of lead-based complex perovskite relaxor ferroelectric single crystals: II. Splitting and assembling of the same type of growth units related to the fluctuation in composition nad structure

Xu Guisheng;LUO HAO;Zhong Weizhao;Yin Zhiwen;Liu Ke   

  1. Shanghai Inst Ceram., CAS.Shanghai(200050)
  • Published:2000-02-15

This paper discusses the relation between the splitting and assembling of the same type growth units and the fluctuation in composition and structure in relaxor ferroelectric single crystals PMNT and PZNT, which belong to lead-based complex perovskite structures. Their growth units are considered as coordination octahedra [BO~6]. Depending on their stability, different [BO~6] growth units in the melt may have different probability to exist. [NbO~6]^7^- and [TiO~6]^8^- are more stable or more favorable octahedral units than [MgO~6]^1^0^- and [ZnO~6]^1^0^-. Various [BO~6] units exhibit remarkable difference in stability, ion size and ion electrovalence. Therefore, the growth interfaces with electric charges would make a choice among those [BO~6] growth units, resulting in the short range of fluctuation in composition and structure at the stage of crystal growth and preparing for the subsequent formation of ordered domains and other chemical defect clusters. Adding the dopant PbTiO~3 to solid solution could adjust the composition and structure of micro-regions and suppress the formation of pyrochlore, which could contribute to the resemblance between the octahedral units [TiO~6]^8^- and [NbO~6]^7^- and the stability effect of [TiO~6]^8^- in crystal structures. This become an important basis for using the modified Bridgman technique to grow pure perovskite PMNT single crystals directly from melt. The evident distinction in growth difficulty between PMNT and PZNT crystals is attributed to the differences between the growth units [MgO~6]^1^0^- and [ZnO~6]^1^0^-. The stability of growth units or structure ones should be taken into consideration when choosing the growth methods.

Key words: PEROVSKITE TYPE STRUCTURE, FERROELECTRIC CRYSTALS, CRYSTAL GROWTH, RELAXATION, MAGNESIUM OXIDE, NIOBIUM OXIDE, LEAD OXIDE

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