Synthesis and Fungicidal Activities of 1-(2-Imidazolonyl)-1,2,4- triazoles

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (10): 1893-1898. Previous Articles

Original Articles

1-(2-咪唑啉酮基)-1H-1,2,4-三唑衍生物的合成与杀菌活性

丁明武;宿亚丽;刘小鹏;刘钊杰

华中师范大学有机合成研究所,武汉(430079)

发布日期:2002-10-15

Synthesis and Fungicidal Activities of 1-(2-Imidazolonyl)-1,2,4- triazoles

Ding Mingwu;Shu Yali;Liu Xiaopeng;Liu Zhaojie

Institute of Organic Synthesis, Central China Normal University, Wuhan(430079)

Published:2002-10-15

Abstract

1-(2-Imidazolonyl)-1,2,4-triazoles(3) were synthesized via tandem aza-Wittig reaction of vinyliminophosphorane (1) with aromatic isocynate and 1H-1,2,4-triazole. The conditions for cyclization were examined. Some of the compounds exhibited good fungicidal activities. The best one was compound 3d showing 100% inhibition of Pyricularia oryzae, Pellicularia sasakii, Fusarium oxysporum, Physalospora piricola and Gibberella zeae as well as 81% inhibition of Cercospora asparagagas at 50 mg/L.

Key words: TRIAZOLE, MIDAZOLONE P, SOCYANIC ESTERS, BACTERICIDAL AGENTS, IMINE

CLC Number:

O627

Cite this article

Ding Mingwu;Shu Yali;Liu Xiaopeng;Liu Zhaojie. Synthesis and Fungicidal Activities of 1-(2-Imidazolonyl)-1,2,4- triazoles[J]. Acta Chimica Sinica, 2002, 60(10): 1893-1898.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Zihao Wang, Min Chen, Changle Chen. Catalytic Synthesis of Polyolefin Elastomer Using Unsymmetrical α-Diimine Nickel Catalyst^★ [J]. Acta Chimica Sinica, 2023, 81(6): 559-564.
[2]	Baomin Yang, Shuitao Zhang, Xian Dong, Guiping Qin, Yubo Jiang. Advances in the Modifications of 4-Monosubstituted 1,2,3-Triazoles [J]. Acta Chimica Sinica, 2023, 81(11): 1577-1589.
[3]	Xia Liu, Chunxiang Kuang, Changhui Su. Transition-metal Catalyzed 1,2,3-Triazole-assisted C—H Functionalization Processes [J]. Acta Chimica Sinica, 2022, 80(8): 1135-1151.
[4]	Yuyin Wang, Xiaoqiang Hu, Hongliang Mu, Yan Xia, Yue Chi, Zhongbao Jian. Enhancement on Nickel-Mediated Ethylene Polymerization by Concerted Steric Hindrance and Fluorine Effect [J]. Acta Chimica Sinica, 2022, 80(6): 741-747.
[5]	Dong Yin, Hongyi Shang, Wenhao Yu, Shikai Xiang, Ping Hu, Keqing Zhao, Chun Feng, Biqin Wang. Synthesis, Mesomorphism and Gelation Properties of Triazole-Modified Triphenylene 2,3-Dicarboxylic Esters and 2,3-Dicarboxyimides [J]. Acta Chimica Sinica, 2022, 80(10): 1376-1384.
[6]	Junyao Xie, Xiaoming Zeng, Meiming Luo. Ni-Catalysed Regioselective α,β-Diarylation of α,β-Unsaturated Aldehydes [J]. Acta Chimica Sinica, 2021, 79(9): 1118-1122.
[7]	Yang Bai, Ling-Wei Xue, Hai-Qiao Wang, Zhi-Guo Zhang. Research Advances on Benzotriazole-based Organic Photovoltaic Materials [J]. Acta Chimica Sinica, 2021, 79(7): 820-852.
[8]	Li Zhewei, Wang Qianyue, Pu Min, Yang Zuoyin, Lei Ming. Theoretical Study on Nitrogenous Heterocyclic Assisted Aldimine Condensation [J]. Acta Chimica Sinica, 2020, 78(5): 437-443.
[9]	Hu Shu-Boa, Chen Mu-Wang, Zhai Xiao-Yong, Zhou Yong-Gui. Synthesis of Tetrahydropyrrolo/indolo[1,2-a]pyrazines by Enantioselective Hydrogenation of Heterocyclic Imines [J]. Acta Chim. Sinica, 2018, 76(2): 103-106.
[10]	Yu Sifan, Fu Xiang, Liu Gengxin, Qiu Huang, Hu Wenhao. Efficient and Facile Synthesis of Chiral Sulfonamides via Asymmetric Multicomponent Reactions [J]. Acta Chim. Sinica, 2018, 76(11): 895-900.
[11]	Shi Minglin, Zhan Gu, Du Wei, Chen Yingchun. Direct Asymmetric Aza-Vinylogous Mannich Reaction of Nitrones from Isatins and Ketimines [J]. Acta Chim. Sinica, 2017, 75(10): 998-1002.
[12]	Wang Yuhui, Cao Zhongyan, Niu Yanfei, Zhao Xiaoli, Zhou Jian. Highly Enantioselective Organocatalytic aza-Henry Reaction of Nitroalkanes to N-Boc Isatin Ketimines [J]. Acta Chimica Sinica, 2014, 72(7): 867-872.
[13]	Gao Dongjing, Hu Hongfan, Cui Chunming. Synthesis and Catalytic Isoprene Polymerization of Rare-Earth Alkyl Complexes Supported by An Arylimine-amidinate Ligand [J]. Acta Chimica Sinica, 2013, 71(08): 1125-1128.
[14]	Li Xinwei, Zhao Bin, Cao Zhengcai, Shen Ping, Tan Songting. Synthesis and Photovoltaic Properties of Conjugated Polymers Based on 1,2,4-Triazole Derivatives [J]. Acta Chimica Sinica, 2012, 70(23): 2433-2439.
[15]	Liu Xiaorui, Chen Chunxiang, He Rongxin, Shen Wei, Li Ming. Theory Design of Two Polymer Donors for Organic Heterojunction Solar Cells [J]. Acta Chimica Sinica, 2012, 70(22): 2365-2371.

1-(2-咪唑啉酮基)-1H-1,2,4-三唑衍生物的合成与杀菌活性

Synthesis and Fungicidal Activities of 1-(2-Imidazolonyl)-1,2,4- triazoles

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments