Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (1): 129-132. Previous Articles     Next Articles

Original Articles

低剪切速率下聚乙二醇/KCl/蒙脱土分散体系的剪切稠化现象

莫小刚;张春光;刘尚营;孙德军;韩书华   

  1. 山东大学,济南(250100)
  • 发布日期:2003-01-15

Effect on Shear Thickening of Polyglycol/KCL/Montmorillonite Dispersion at Low Shear Rates

Mo Xiaogang;Zhang Chunguang;Liu Shangying;Sun Dejun;Han Shuhua   

  1. Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Shandong University,Jinan 250100
  • Published:2003-01-15

The viscosity of dispersion of polyglycol/KCl/montmorillonite as shear rate increases is studied by RS75 Haake rheometer. It turns out that the dispersion shows a complex transition process of shear- thinning → shear-thickening → shear-thinning as the increase of shear rate when polyglycol and KCl are present together in a certain range of concentrations, shear thickening weakens gradually. The photographs of TEM indicate that KCl causes montmorillonite to aggregate together and polyglycol solely leads to slight flocculation in montmorillonite dispersion. When both of them are present, the dispersion forms sterically stable state of strip structure.

Key words: SHEAR RATE, POLYGLYCOL, DISPERSE SYSTEM, THICKENERS, RHEOLOGY, PHENOMENA, POTASSIUM CHLORIDE, TRANSMISSION ELECTRON MICROSCOPY

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