Synthesis of Monodispersed ZnO Nanorod Array Films by Chemical Solution Deposition

Abstract

Monodispersed and well-aligned ZnO nanorod arrays have been synthesized by chemical solution deposition on spin-coated and preheated ZnO sol films. The diameter of ZnO nanorods was controllable by adjusting the process of nano-ZnO film substrates. The morphology and crystalline structures of ZnO nanorods were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and X-ray diffraction (XRD). The room temperature photoluminescence spectrum of the as-prepared ZnO nanorod arrays exhibits a strong UV emission at about 384 nm and no defects related visible emissions.

Key words: ZnO, nanorod array, chemical solution deposition

Cite this article

LUO Zhi-Qiang, ZHANG Xiao-Bin*^,1, CHENG Ji-Peng, TAO Xin-Yong, LI Yu, LIU Fu, TANG Xiao-Ming², WANG You-Wen². Synthesis of Monodispersed ZnO Nanorod Array Films by Chemical Solution Deposition[J]. Acta Chimica Sinica, 2005, 63(18): 1656-1660.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Zhiqiang Wang, Jinzhan Su. Investigation of the Kinetic Properties and Photoelectrochemical Water Splitting of Cu₃V₂O₈/ZnO Photoanode Modified by Cobalt Phosphate [J]. Acta Chimica Sinica, 2024, 82(1): 26-35.
[2]	Juan Wang, Huamin Xiao, Ding Xie, Yuanru Guo, Qingjiang Pan. Density Functional Theory Study of Structures of Copper-doped and Graphitic Carbon Nitride-combined Zinc Oxides and Their Boosted Nitrogen Dioxide-sensing Performance [J]. Acta Chimica Sinica, 2023, 81(11): 1493-1499.
[3]	Ni Yuxin, Zhang Chenjie, Yuan Yaxian, Xu Minmin, Yao Jianlin. Determination on Origination of Surface Enhanced Raman Scattering Effect on Nano ZnO Substrate [J]. Acta Chim. Sinica, 2019, 77(7): 641-646.
[4]	Meng Shuangyan, Wang Mingming, Lü Bolin, Xue Qunji, Yang Zhiwang. Preparation of Eu-Doped ZnO/MIL-53(Fe) Photocatalyst and Its Catalytic Performance for Selective Oxidation of Alcohols [J]. Acta Chimica Sinica, 2019, 77(11): 1184-1193.
[5]	Hao Yanzhong, Fan Longxue, Sun Bao, Sun Shuo, Pei Juan. A Photoelectrochemical Study of p-n Heterojunction between P3HT and Nanodendrite CdTe Sensitized ZnO Nanotube Array [J]. Acta Chimica Sinica, 2014, 72(1): 114-120.
[6]	Xie Yunlong, Zhong Guo, Du Gaohui. Preparation and Characterization of ZnS and ZnS/ZnO Heterostructure Nanowire by Chemical Vapor Deposition [J]. Acta Chimica Sinica, 2012, 70(10): 1221-1226.
[7]	Hao Yanzhong, Cao Yinhu, Sun Bao, Zhang Yanhui, Li Yingpin, Xu Dongsheng, Li Xiangling. Fabrication of Ordered One-dimensional P3HT/CdS/TiO₂/ZnO Core-Shell Nanorod Array and Their Application to Hybrid Solar Cell [J]. Acta Chimica Sinica, 2012, 70(10): 1139-1144.
[8]	Fan Gaochao, Huang Zaiyin, Chen Jie, Ma Yujie. Impact of Size Effects on the Thermodynamic Properties of Zinc Oxide Micro/nano System [J]. Acta Chimica Sinica, 2012, 70(07): 938-942.
[9]	ZHENG Jian-Hua, ZHANG Xiao-Kai, LU Hui-Fen. Synthesis and Characterization of Well-aligned ZnO Nanorod Arrays under Specific Conditions [J]. Acta Chimica Sinica, 2011, 69(20): 2434-2438.
[10]	SONG Ji-Zhong, HE Ying, PAN Zhao-Dong, ZHU Di, CHEN Jie, WANG Jun-An. PANI/nano-ZnO Composites Prepared by In-situ Polymerization under Magnetic Field [J]. Acta Chimica Sinica, 2011, 69(13): 1582-1588.
[11]	ZHAO Bin, ZHAO Su-Qing, ZHANG Kun, LIU Duan, SU Juan. Preparation and Characterization of Thiourea Modified Water-Soluble Cd Doped ZnO Quantum Dots [J]. Acta Chimica Sinica, 2011, 69(07): 777-782.
[12]	LI Zhong, LIU Yan, HE Zhong, FAN Hui, ZHENG Hua-Yan. Effects of Cu/Zn on the Structure and Activity of CuO/ZnO/Al₂O₃Catalysts Prepared under Microwave Irradiation in Aging Process [J]. Acta Chimica Sinica, 2011, 69(05): 570-576.
[13]	LIU Xiao-Yu, GUO Ping-Jun, ZHOU Gong-Bing, PEI Yan, QIAO Ming-Hua, FAN Kang-Nian. Cu/ZnO Water-gas Shift Catalysts Calcined at Different Temperatures for Shut-down/Start-up Operation [J]. Acta Chimica Sinica, 2010, 68(24): 2523-2528.
[14]	LI Chang-Quan, LUO Lai-Chao, XIONG Guang-Wei. Study of the Preparation and Photocatalysis Performance of CeO₂/ZnO Mixed Nanometer Tubes [J]. Acta Chimica Sinica, 2010, 68(10): 1023-1026.
[15]	. Synthesis of Aligned ZnO Submicron Rod Arrays by Heating Zinc Foil Covered with ZnCl2 Solution [J]. Acta Chimica Sinica, 2009, 67(13): 1515-1522.

化学溶液沉积法制备单分散氧化锌纳米棒阵列