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Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (3): 191-197.     Next Articles

几个超分子体系中非常规键的AIM分析

朱瑞新1，祝诗发1，周俊红2，陈敏伯*,1,2   

  1. (1中国科学院上海有机化学研究所 上海 200032)
    (2华东理工大学化学系 上海 200237)
  • 投稿日期:2005-10-12 修回日期:2005-12-19 发布日期:2006-02-14
  • 通讯作者: 陈敏伯

AIM Analysis of Unconventional Bonds in Some Supramolecular Systems

  1. (1 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032)
    (2 Department of Chemistry, East China University of Science and Technology, Shanghai 200237)
  • Received:2005-10-12 Revised:2005-12-19 Published:2006-02-14
  • Contact: CHEN Min-Bo

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Five crystals containing fluorine atoms were prepared. The electronic structures of these crystals were studied theoretically and a lot of unconventional weak interaction were found. Particularly, one of these crystals was self-assembled by overwhelming weak F…O bonds, not hydrogen bonds.