Synthesis, Characterization and CD Spectrum of Porphyrin Derivatives with Circularly Polarized Property

Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (10): 977-982. Previous Articles Next Articles

Original Articles

具有圆偏振光特性的卟啉衍生物的合成、表征和CD光谱研究

骆开均¹,2, 晋军³, 谢明贵*^,2, 蒋青², 徐玲玲¹

(¹四川师范大学化学与材料学院成都 610068)
(²四川大学化学学院成都 610064)
(³四川大学分析测试中心成都 610064)

投稿日期:2006-06-20 修回日期:2006-11-27 发布日期:2007-05-28
通讯作者: 谢明贵

Synthesis, Characterization and CD Spectrum of Porphyrin Derivatives with Circularly Polarized Property

LUO Kai-Jun¹,2; JIN Jun³; XIE Ming-Gui*^,2; JIANG Qing²; XU Ling-Ling¹

(¹Institute of Chemistry and Materials, Sichuan Normal University, Chengdu 610068)
(²Institute of Chemistry, Sichuan University, Chengdu 610064)
(³Testing Centre of Sichuan University, Chengdu 610064)

Received:2006-06-20 Revised:2006-11-27 Published:2007-05-28
Contact: XIE Ming-Gui

Abstract

A series of porphyrin compounds and Zn complexes with cholesterol ester side chains were synthesized and their UV-Vis and fluorescence spectrum were tested. CD spectrum showed that these compounds in polymethyl methacrylate (PMMA) solid film had circular dichroism property in soret and Q bands because of mutual coupling between chiral cholesterol ester moieties and tetraphenylporphyrin ring, furthermore, it was found that the CD spectrum of cholesterol ester porphyrin compounds was changed along with concentration of these compounds in PMMA solid film.

Key words: cholesterol ester side chain, porphyrin compound, circular dichroism, circularly polarized luminescence

Cite this article

LUO Kai-Jun^1,2; JIN Jun³; XIE Ming-Gui*^,2; JIANG Qing²; XU Ling-Ling. Synthesis, Characterization and CD Spectrum of Porphyrin Derivatives with Circularly Polarized Property[J]. Acta Chimica Sinica, 2007, 65(10): 977-982.

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具有圆偏振光特性的卟啉衍生物的合成、表征和CD光谱研究

Synthesis, Characterization and CD Spectrum of Porphyrin Derivatives with Circularly Polarized Property

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