RuB-PVP Colloidal Catalysts: Preparation and Catalytic Performance in Selective Hydrogenation of Benzene to Cyclohexene

Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (14): 1338-1342. Previous Articles Next Articles

Original Articles

RuB-PVP胶态催化剂的制备及苯选择加氢性能研究

卜娟¹, 王建强¹, 乔明华*^,1, 闫世润¹, 李和兴², 范康年*^,1

(¹复旦大学化学系上海市分子催化和创新材料重点实验室上海 200433)
(²上海师范大学化学系上海 200234)

投稿日期:2006-03-10 修回日期:2007-03-01 发布日期:2007-07-28
通讯作者: 乔明华

RuB-PVP Colloidal Catalysts: Preparation and Catalytic Performance in Selective Hydrogenation of Benzene to Cyclohexene

BU Juan¹; WANG Jian-Qiang¹; QIAO Ming-Hua*^,1; YAN Shi-Run¹; LI He-Xing²; FAN Kang-Nian*^,1

(¹Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433)
(²Department of Chemistry, Shanghai Normal University, Shanghai 200234)

Received:2006-03-10 Revised:2007-03-01 Published:2007-07-28
Contact: QIAO Ming-Hua

Abstract

A series of polyvinylpyrrolidone (PVP)-stabilized RuB colloidal catalysts have been successfully prepared with the diameters of RuB in the range of 1.3～3.9 nm with narrow size distribution. In benzene selective hydrogenation, it was found that the RuB-PVP catalyst with smaller particle size exhibited higher activity and selectivity. Moreover, the RuB-PVP catalysts have much better performance than the RuB catalyst without the stabilization of PVP under the same reaction condition.

Key words: RuB, PVP, benzene, cyclohexene, selective hydrogenation

Cite this article

BU Juan; WANG Jian-Qiang; QIAO Ming-Hua*^,1; YAN Shi-Run; LI He-Xing²; FAN Kang-Nian*^,1. RuB-PVP Colloidal Catalysts: Preparation and Catalytic Performance in Selective Hydrogenation of Benzene to Cyclohexene[J]. Acta Chimica Sinica, 2007, 65(14): 1338-1342.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Bin Xu, Xiuzhi Wei, Jiangmin Sun, Jianguo Liu, Longlong Ma. In-situ Synthesis of Nitrogen-doped Graphene Layer Encapsulated Palladium Nanoparticles for Highly Selective Hydrogenation of Vanillin [J]. Acta Chimica Sinica, 2023, 81(3): 239-245.
[2]	Luocong Wang, Zhewei Li, Caiwei Yue, Peihuan Zhang, Ming Lei, Min Pu. Theoretical Study on the Isomerization Mechanism of Azobenzene Derivatives under Electric Field [J]. Acta Chimica Sinica, 2022, 80(6): 781-787.
[3]	Bo Wu, Chong Wang, Baolin Li, Chunru Wang. Light-driven Molecular Magnetic Switch for a Metallofullerene^※ [J]. Acta Chimica Sinica, 2022, 80(2): 101-104.
[4]	Yeming Wang, Hongwei Wang, Zhaohong Liu. Research Progress on EWG-Substituted N-Arylsulfonylhydrazones as the Diazo Compound Precursor [J]. Acta Chimica Sinica, 2021, 79(9): 1085-1096.
[5]	Min Zhao, Xue Wang, Yanan Liu, Yufei He, Dianqing Li. Preparation of Efficient Pd/MgAl-LDO@Al₂O₃ Catalyst for Phenol Hydrogenation to Cyclohexanone [J]. Acta Chimica Sinica, 2021, 79(12): 1518-1525.
[6]	Ni Liao, Xia Zhong, Wen-Bin Liang, Ruo Yuan, Ying Zhuo. Metal-organic Frameworks (MOF)-based Novel Electrochemiluminescence Biosensing Platform for Quantification of H₂O₂ Releasing from Tumor Cells [J]. Acta Chimica Sinica, 2021, 79(10): 1257-1264.
[7]	Ling-Yan Li, Wei Zheng, Cheng-Hui Li. A Facile Synthetic Method and New Derivatives of Phthalorubines [J]. Acta Chimica Sinica, 2021, 79(1): 81-86.
[8]	Liu Xiaojun, Qin Lang, Zhan Yuanyuan, Chen Meng, Yu Yanlei. Phototuning of Structural Colors in Cholesteric Liquid Crystals [J]. Acta Chimica Sinica, 2020, 78(6): 478-489.
[9]	Wang Zhiqiang, Bai Meidan, Zhang Ming, Zhang Zhiqiang, Feng Xun, Zheng Caijun. Synthesis and Properties of Two Novel Thermally Activated Delayed Fluorescence Materials with 1,3,5-Tribenzoylbenzene as Electron-Acceptor [J]. Acta Chimica Sinica, 2020, 78(2): 140-146.
[10]	Yao Xuting, Huang Xin, Lin Yuxia, Liu Yueming. Deactivated TS-1 as Efficient Catalyst for Hydration of Cyclohexene to Cyclohexanol [J]. Acta Chimica Sinica, 2020, 78(10): 1111-1119.
[11]	He Yuanyuan, Cheng Na, Zhao Jianwei. Electron Transport Pathways Through One-Dimensional Conjugated Carbon Chain Doped by Thiophene Ring [J]. Acta Chim. Sinica, 2017, 75(9): 893-902.
[12]	Cai Yuejin, Liu Chenxia, Zhuo Ou, Wu Qiang, Yang Lijun, Chen Qiang, Wang Xizhang, Hu Zheng. Ruthenium Nanoparticles Supported on Hierarchical Nitrogen-Doped Carbon Nanocages for Selective Hydrogenation of Acetophenone in Mild Conditions [J]. Acta Chim. Sinica, 2017, 75(7): 686-691.
[13]	Zhou Gongbing, Wang Hao, Pei Yan, Qiao Minghua, Sun Bin, Zong Baoning. Pore Size Effect of Ru-Zn/ZrO₂ Catalyst on Partial Hydrogenation of Benzene to Cyclohexene [J]. Acta Chim. Sinica, 2017, 75(3): 321-328.
[14]	Dou Rongfei, Tan Xiaohe, Fan Yiqiu, Pei Yan, Qiao Minghua, Fan Kangnian, Sun Bin, Zong Baoning. Study on Ru-B/MIL-53(Al_xCr₁) Catalysts for Partial Hydrogenation ofBenzene to Cyclohexene [J]. Acta Chim. Sinica, 2016, 74(6): 503-512.
[15]	Zhao Qing, Qi Boyu, Wang Baojin, Chen Feiwu. Theoretical Investigation on Weak Interactions of HXeBr with Benzene and Its Derivatives [J]. Acta Chim. Sinica, 2016, 74(3): 285-292.

RuB-PVP胶态催化剂的制备及苯选择加氢性能研究

RuB-PVP Colloidal Catalysts: Preparation and Catalytic Performance in Selective Hydrogenation of Benzene to Cyclohexene

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments