Baeyer-Villiger Oxidation of Cyclohexnanone to Caprolactone over Highly Efficient MgO/SnO2 Catalyst

Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (1): 5-9. Previous Articles Next Articles

Original Articles

高活性MgO/SnO2复合金属氧化物催化剂的合成及在双氧水选择氧化环己酮制ε-己内酯反应中的应用

李静霞，黄靓，戴维林*，范康年

复旦大学化学系

投稿日期:2007-06-22 修回日期:1900-01-01 发布日期:2008-01-14
通讯作者: 戴维林

Baeyer-Villiger Oxidation of Cyclohexnanone to Caprolactone over Highly Efficient MgO/SnO2 Catalyst

LI Jing-Xia; HUANG Jing; DAI Wei-Lin;* FAN Kang-Nian

(Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433)

Received:2007-06-22 Revised:1900-01-01 Published:2008-01-14
Contact: FAN Kang-Nian

Abstract

A series of Mg-based catalysts were prepared by the coprecipitation method and were characterized by XRD, BET, and TG-DTA. As compared with other composite catalysts, including MgO/Al2O3, MgO/La2O3, MgO/TiO2, MgO/ZnO, and MgO/ZrO2, MgO/SnO2 showed the most efficient catalytic performance in the Baeyer-Villiger oxidation of cyclohexanone to ε-caprolactone with aqueous hydrogen peroxide as oxidant. Under optimal reaction conditions, the as-prepared MgO/SnO2 catalyst after calcined at 600℃ with the Mg/Sn molar ratio of 7:3 presents an excellent performance with the cyclohexanone conversion of 90.5% and the caprolactone selectivity of 100%.

Key words: MgO/SnO₂ composite, cyclohexanone, Baeyer-Villiger oxidation

Cite this article

LI Jing-Xia; HUANG Jing; DAI Wei-Lin;* FAN Kang-Nian . Baeyer-Villiger Oxidation of Cyclohexnanone to Caprolactone over Highly Efficient MgO/SnO2 Catalyst[J]. Acta Chimica Sinica, 2008, 66(1): 5-9.

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[1]	Min Zhao, Xue Wang, Yanan Liu, Yufei He, Dianqing Li. Preparation of Efficient Pd/MgAl-LDO@Al₂O₃ Catalyst for Phenol Hydrogenation to Cyclohexanone [J]. Acta Chimica Sinica, 2021, 79(12): 1518-1525.
[2]	Li Baole, Liu Renrong, Liang Renxiao, Jia Yixia. Palladium/Amino Acid Co-Catalyzed Intramolecular α-Vinylation of Cyclohexanones [J]. Acta Chim. Sinica, 2017, 75(5): 448-452.
[3]	Zou Xue, Wang Hongmei, Lu Yan, Huang Chaoqun, Xia Lei, Chen Xiaojing, Shen Chengyin, Chu Yannan. Rapid Analysis of Residual Cyclohexanone in PVC Infusion Set by Extractive Electrospray Ionization-Mass Spectrometer/Mass Spectrometer [J]. Acta Chim. Sinica, 2015, 73(8): 851-855.
[4]	XUE Xiao-Jin, SUN Qiong, WANG Yan, LV Kang-Le, HU Yi-Ming. Effect of Fluoride Ions on the Selective Photocatalytic Oxidation of Cyclohexane over TiO₂ [J]. Acta Chimica Sinica, 2010, 68(06): 471-475.
[5]	ZHANG Chao-Xin; DA Shi-Jun; ZHANG Hua-Bing; SUN Bin; LI Ying. Asymmetric Total Synthesis of (＋)-Disparlure: (＋)-(7R,8S)-cis-7,8- ep-oxy-2-methyloctadecane [J]. Acta Chimica Sinica, 2007, 65(21): 2433-2436.
[6]	GUO Ming-Lin. Quaternary Ammonium Decatungstate Catalyst for Cyclohexanol to Cyclohexanone [J]. Acta Chimica Sinica, 2004, 62(19): 1956-1958.
[7]	Mao Dongsen;Lu Guanzhong;Chen Qingling;Xie Zaiku;Zhang Yuxian. Vapor-phase beckmann rearrangement of cyclohexanone oxime over modified titania-zirconia catalyst [J]. Acta Chimica Sinica, 2001, 59(7): 1139-1144.
[8]	Li Ping;Lu Guanzhong;Luo Yong;Dai Yanan. Study on catalytic oxidation activity of TS zeolite 5: Ammoximation of cyclohexanone [J]. Acta Chimica Sinica, 2000, 58(2): 204-208.
[9]	GUO CANCHENG;ZHANG XIAOBING;HOU LIANBO;XU JIANBING;HAO XUDONG;GUO ANMING;LIANG BENXI;CHEN XINBIN. Study on the mechanism of cyclohexanone formation in cyclohexane hydroxylation catalyzed by metalloporphyrins [J]. Acta Chimica Sinica, 1998, 56(5): 489-494.
[10]	GUO CANCHENG. Synthesis of porphyrin compounds and their imitation for cytochrome P-450. 12.μ-Oxo-bisiron(Ⅲ)porphyins-catalyzed monooxygenation of cyclohexane [J]. Acta Chimica Sinica, 1994, 52(4): 367-372.
[11]	YE XIULIN. Studies on the reactions of the enamines and enols of 4,4 -ethylenedioxo-cyclohexanone and its 2-carbaldehyde and 2-carboxylic ester [J]. Acta Chimica Sinica, 1993, 51(12): 1214-1220.
[12]	TIE HONG;MA ZHENKUN;LI LIANGZHU;ZHANG PANG. o-nitrobenzoylation of some enamines and rearrangements involved in acid hydrolysis [J]. Acta Chimica Sinica, 1990, 48(7): 720-725.
[13]	CHEN FANGPING;ZHANG YONGHUA. A new type of ion-selective electrode for nonaqueous solution: Assumption of water-membrane electrode [J]. Acta Chimica Sinica, 1989, 47(2): 174-177.
[14]	ZHAO ZHENGUO;ZHANG LANHUI;LIN. Adsorption of cyclohexanone and benzoic acid from cyclohexane onto silica gel [J]. Acta Chimica Sinica, 1988, 46(1): 53-56.
[15]	ZHANG DIANKUN. Nuclear magnetic resonance of organophosphorus compounds I.1H, 31P and 13C NMR spectra of 1,32-benzoxazaphosphorin-4-one derivatives [J]. Acta Chimica Sinica, 1987, 45(10): 1014-1019.

高活性MgO/SnO2复合金属氧化物催化剂的合成及在双氧水选择氧化环己酮制ε-己内酯反应中的应用

Baeyer-Villiger Oxidation of Cyclohexnanone to Caprolactone over Highly Efficient MgO/SnO2 Catalyst

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