Studies on Atom Transfer Radical Polymerization of Phenoxyallene

Acta Chimica Sinica ›› 2009, Vol. 67 ›› Issue (16): 1897-1902. Previous Articles Next Articles

Original Articles

酚氧基联烯基醚单体的原子转移自由基聚合研究

张晓鸿a 袁丽a 杨东a 胡建华*,a 陈晓枫b 王利b

(a聚合物分子工程教育部重点实验室复旦大学先进材料实验室复旦大学高分子科学系上海 200433)
(b复旦大学分析测试中心上海 200433)

投稿日期:2009-07-06 修回日期:2009-07-22 发布日期:2009-08-28
通讯作者: 胡建华

Studies on Atom Transfer Radical Polymerization of Phenoxyallene

Zhang, Xiaohong^a Yuan, Li ^a Yang, Dong ^a Hu, Jianhua ^*,a
Chen, Xiaofeng^b Wang, Li ^b

(^a Key Laboratory of Molecular Engineering of Polymers Ministry of Education, Laboratory of Advanced Materials,
Department of Macromolecular Science, Fudan University, Shanghai 200433)
(^b Center of Analysis and Measurement, Fudan University, Shanghai 200433)

Received:2009-07-06 Revised:2009-07-22 Published:2009-08-28
Contact: Hu Jian-Hua

Abstract

Atom transfer radical polymerizations (ATRP) of phenoxyallene (POA) and p-tert-butyl phenoxyallene (t-BuPOA) were studied using different initiators and ligands. It was found that the polymerization of POA followed the mechanism of ATRP both in the systems of methyl 2-bromopropanoate/CuBr/4,4’-diheptyl-2,2’-bipyridine (2-MBP/CuBr/dHbpy) and p-toluene sulfonyl chloride/CuBr/tris-[2-(dimethylamino)ethyl]amine (p-TsCl/CuBr/Me6TREN).

Key words: phenoxyallene, atom transfer radical polymerization (ATRP), controlled radical polymerization

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酚氧基联烯基醚单体的原子转移自由基聚合研究

Studies on Atom Transfer Radical Polymerization of Phenoxyallene

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