Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (13): 1540-1544. Previous Articles     Next Articles

Full Papers

复合碱媒介法合成棒状CdTe晶体

项东虎, 朱亚波*, 罗锦, 郭立童   

  1. (中国矿业大学材料科学与工程学院 徐州 221116)
  • 投稿日期:2011-04-01 修回日期:2011-05-19 发布日期:2011-06-01
  • 通讯作者: 朱亚波 E-mail:zhuyabo@163.com
  • 基金资助:

    中央高校基本科研业务费专项资金;江苏省自然科学基金

Synthesis of CdTe Micro-crystal Rods by Composite- hydroxide-mediated Method

XIANG Dong-Hu, ZHU Ya-Bo, LUO Jin, GUO Li-Tong   

  1. (School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116)
  • Received:2011-04-01 Revised:2011-05-19 Published:2011-06-01

CdTe micro-crystal has been successfully synthesized by composite-hydroxide-mediated method (CHM) using Te and Cd(NO3)2 as the reactants and hydrazine hydrate as reductant. The rod- and cube-shaped CdTe have been obtained under the different reacting conditions. The length of the rods was up to about several decades of micrometers. It will be helpful to the forming of rod-shaped CdTe with appropriate deionized water added into the reacting system at temperature of 180 ℃. Here a new model was proposed to describe the growth for CdTe crystal. XRD pattern indicates that rods were well crystallized. UV-visible absorption spectrum of the rods exhibits a peak in infrared region, and the band gap of the CdTe micro-crystal is about 1.49 eV.

Key words: CdTe, composite-hydroxide-mediated method (CHM), absorption spectrum, band gap

CLC Number: