Study of novel compounds containing both thiophosphate  and pyrethroid skeleton III. The reaction of ketoximes (or  aldoximes) of 3-alkoxycarbonyl-2, 2-dimethyl-cyclopropyl  with chlorothiophosphates

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (1): 98-101. Previous Articles

Original Articles

含磷拟除虫菊酯的研究III. 3-烷氧羰基-2, 2-二甲基环丙烷基甲醛肟或甲基酮肟和二烷氧基硫代磷酰氯的反应

邵瑞链;张和胜;王水平

南开大学元素有机化学研究所.天津(300071)

发布日期:1991-01-15

Study of novel compounds containing both thiophosphate and pyrethroid skeleton III. The reaction of ketoximes (or aldoximes) of 3-alkoxycarbonyl-2, 2-dimethyl-cyclopropyl with chlorothiophosphates

Shao Ruilian;Zhang Hesheng;Wang Shuiping

Nankai Univ, Elementoorgan Chem Lab.Tianjin(300071)

Published:1991-01-15

Abstract

The thiophosphate derivatives of (3-alkoxycarbonyl-2, 2-dimethyl) cyclopropyl methyl ketoximes (1) were prepared by the reaction of oximes of 3-acetyl, 2, 2-dimethyl-cyclopropylcarboxylates with chlorothiophosphates. The reaction of 3-ethoxycarbonyl-2, 2- dimethylcycllopropylaldoxime with chlorothiophosphates in the presence of bases yielded unstable oximino-esters which was decomposed through Beckmann fragmentation to give nitrile and the corresponding thiophosphoric acid.

Key words: THIOPHOSPHORYL CHLORIDE, FORMALDOXIME, ALKOXYCARBONYL GROUP, SYNTHETIC PYRETHROID-INSECTICIDES

CLC Number:

TQ45

Cite this article

Shao Ruilian;Zhang Hesheng;Wang Shuiping. Study of novel compounds containing both thiophosphate and pyrethroid skeleton III. The reaction of ketoximes (or aldoximes) of 3-alkoxycarbonyl-2, 2-dimethyl-cyclopropyl with chlorothiophosphates[J]. Acta Chimica Sinica, 1991, 49(1): 98-101.

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[1]	REN Yuan-Lin*; CHENG Bo-Wen; ZHANG Jin-Shu; ZANG Hong-Jun; KANG Wei-Min; DING Chang-Kun. Synthesis, Crystal Structure and Thermal Properties of N,N'-Di(diethoxythiophosphoryl)-1,4-phenylenediamine [J]. Acta Chimica Sinica, 2007, 65(18): 2034-2038.
[2]	LIANG Guo-Ming, REN Yi. Theoretical Study of the Tautomerization of Nitromethane to Formaldoxime in Aqueous Solution [J]. Acta Chimica Sinica, 2005, 63(23): 2163-2168.
[3]	Li Zhongfang;Fu Fangxin;Pan Huade;Xing Yan;Lin Yonghua. Synthesis,structure charaterization of the complexes of β- alkoxycarbonylethyltin trichlorides with schiff base ligands [J]. Acta Chimica Sinica, 1999, 57(7): 820-830.
[4]	DING YU;SHEN MIAO. The sysnthesis of (±) cis-3-(dichlorovinyl)-2,2-dimethyl- cyclopropanecarboxylic acid [J]. Acta Chimica Sinica, 1992, 50(7): 722-725.
[5]	CHEN RUYU;SHAO RUILIAN;ZHANG HESHEN;WANG SHUIPING. Study of nw compounds containing both phosphorus and pyrethroid skeleton I: Synthesis of 3-[1'-(substituted phosphinyloxy)-2'-chlorovinyl]-2,-dimethylcyclopropane carboxylate and study of its geometrical isomer [J]. Acta Chimica Sinica, 1990, 48(4): 388-392.
[6]	SHAO RUILIAN;WANG SHUIPING;CHENG JUNRAN. Study of novel compounds containing both phosphorus and pyrethroid skeleton II: Synthesis of compounds containing bicyclic phosphate and 3-substituted-2,2-dimethylcyclopropane carboxylate and study of its reaction [J]. Acta Chimica Sinica, 1990, 48(4): 393-398.
[7]	CHEN RUYU;LI YUGUI;ZHAI PEIJIAN. Synthesis of m-phenoxy-\a-cyanobenzyl-\a-(O-alkyl-O-alkyl(phenyl)dithiophosphor(on)yl) isovalerates [J]. Acta Chimica Sinica, 1986, 44(11): 1122-1128.
[8]	DING WEIYU;CAI WEN;PU JIAQI;SHEN WEIPING;DAI JINSHAN. Studies on the application of elemento-organic compounds of the fifth and sixth groups in organic syntheses xxiii. the decomposition of carboalkoxy-alkyltriphenylphosphonium halides in dmf [J]. Acta Chimica Sinica, 1985, 43(1): 53-56.

含磷拟除虫菊酯的研究III. 3-烷氧羰基-2, 2-二甲基环丙烷基甲醛肟或甲基酮肟和二烷氧基硫代磷酰氯的反应

Study of novel compounds containing both thiophosphate and pyrethroid skeleton III. The reaction of ketoximes (or aldoximes) of 3-alkoxycarbonyl-2, 2-dimethyl-cyclopropyl with chlorothiophosphates

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含磷拟除虫菊酯的研究III. 3-烷氧羰基-2, 2-二甲基环丙烷基 甲醛肟或甲基酮 肟和二烷氧基硫代磷酰氯的反应

Study of novel compounds containing both thiophosphate and pyrethroid skeleton III. The reaction of ketoximes (or aldoximes) of 3-alkoxycarbonyl-2, 2-dimethyl-cyclopropyl with chlorothiophosphates

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Abstract

Cite this article

share this article

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含磷拟除虫菊酯的研究III. 3-烷氧羰基-2, 2-二甲基环丙烷基甲醛肟或甲基酮肟和二烷氧基硫代磷酰氯的反应