Supramolecular System of Alkoxyphenylporphyrin with Cyclodextrins

Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (21): 2391-2396. Previous Articles Next Articles

Original Articles

烷氧基苯基卟啉与环糊精的超分子体系研究

胡羽a 赵鸿斌*,a,b 宁静恒c 宁满霞b 徐勇军b
仇诗军a 廖俊旭a

(a湘潭大学化学学院湘潭 411105)
(b东莞理工学院化学生物工程系东莞 523808)
(c长沙理工大学化学与环境工程学院长沙 410076)

投稿日期:2008-01-07 修回日期:2008-04-24 发布日期:2008-11-14
通讯作者: 赵鸿斌

Supramolecular System of Alkoxyphenylporphyrin with Cyclodextrins

HU, Yu ^a ZHAO, Hong-Bin ^*,a,b NING, Jing-Heng^c NING, Man-Xia ^b XU, Yong-Jun ^b QIU, Shi-Jun ^a LIAO, Jun-Xu ^a

(a College of Chemistry, Xiangtan University, Xiangtan 411105)
(b Faculty of Chemical Biotechnology, Dongguan University of Technology, Dongguan 523808)
(c College of Chemistry and Environment Engineering, Changsha University of Science and Technology, Changsha 410076)

Received:2008-01-07 Revised:2008-04-24 Published:2008-11-14

Abstract

Water-unsolvable alkoxyphenylporphyrins were synthesized, and their supramolecular systems with cyclodextrins (CD) have been examined by means of UV-Vis, fluorescence spectrometry and 1H NMR technique. The formation ratio and binding constants of the supramolecular systems were determined by fluorescence spectrometry and an elementary research on its mechanism was performed. The influence of different substituent positions and different lengths of the alkoxy chain on the supramolecular systems of the water-unsolvable alkoxyphenylporphyrin with CD of different cavity diameters was also discussed.

Key words: alkoxyphenylporphyrin, cyclodextrin, supramolecular system, formation ratio, binding constant

Cite this article

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Qie Shuyan, Hao Ying, Liu Zongjian, Wang Jin, Xi Jianing. Advances in Cyclodextrin Polymers and Their Applications in Biomedicine [J]. Acta Chimica Sinica, 2020, 78(3): 232-244.
[2]	Zhou Wei-Lei, Chen Yong, Liu Yu. Lanthanide Luminescent Supramolecular Assembly Based on Cyclodextrin [J]. Acta Chimica Sinica, 2020, 78(11): 1164-1176.
[3]	Zhang Yi, Chen Yong, Li Jingjing, Liang Lu, Liu Yu. Construction and Luminescent Behavior of Supramolecular Hydrogel with White-Light Emission [J]. Acta Chim. Sinica, 2018, 76(8): 622-626.
[4]	Zhang Lifang, Zhao Jie, Wang Yong. Construction and Chromatographic Performance of a Novel Triazole Bridged Hybrid Bilayer Cyclodextrin Chiral Stationary Phase [J]. Acta Chim. Sinica, 2015, 73(11): 1182-1188.
[5]	Zhou Rendan, Li Laisheng, Cheng Biaoping, Nie Guizhen, Zhang Hongfu. Preparation and Evaluation of a Novel bis(β-cyclodextrin)-bonded SBA-15 Chiral Stationary Phase for HPLC [J]. Acta Chimica Sinica, 2014, 72(6): 720-730.
[6]	Kong Rui, Shi Dongjian, Liu Rongjin, Wu Chao, Ni Peihong, Chen Mingqing. Preparation and Properties of Supramolecular Aggregation of Dual-Sensitive Cyclodextrins [J]. Acta Chimica Sinica, 2013, 71(11): 1540-1546.
[7]	Zou Qiong, Liu Juan, Zhu Gangbing, Zhang Xiaohua, Chen Jinhua. Construction and Performance of a New Bioanode for Biofuel Cells [J]. Acta Chimica Sinica, 2013, 71(08): 1154-1160.
[8]	He Xiaodan, Xu Chongsheng, Chu Yanqiu, Ding Chuanfan. Investigation on Non-Covalent Complexes of Cyclodextrins with GGG and GFF Tripeptides in Gas Phase by Mass Spectrometry [J]. Acta Chimica Sinica, 2013, 71(03): 397-404.
[9]	Gao Peng, Wang Peijing, Geng Xue, Ye Lin, Zhang Aiying, Feng Zengguo. A Study on Properties of PEG Bent Double Chain Stranded Polypseudorotaxanes with γ-Cyclodextrins [J]. Acta Chimica Sinica, 2013, 71(03): 347-350.
[10]	Han Cong, Xu Zhe, Diao Chunhua, Chen Xin, Liu Jing, Guo Minjie, Fan Zhi. Self-assembly Behavior of Interlocked Helical Supramolecule of Cyclodextrin Modified by 2-Furanmethanethiol [J]. Acta Chimica Sinica, 2013, 71(03): 439-442.
[11]	Zhang Xiaojun, Liu Shangzhong, Wu Xuemin, Li Shujing. Supramolecular Hydrogels Obtained by Host-Guest Interactions of Cyclodextrin Dimers with Viologen Polymer [J]. Acta Chimica Sinica, 2012, 70(19): 2066-2072.
[12]	Wang Huaisong, Peng Jiangtao, Wei Jiping, Jiang An. Synthesis of Novel Chiral Stationary Phase Based on Atom Transfer Radical Polymerization and Click Chemistry [J]. Acta Chimica Sinica, 2012, 70(12): 1355-1361.
[13]	Li Shujing, Zhang Xiaojun, Liang Haiyan, Wang Xinrui. Supramolecular Hydrogels Obtained by Host-Guest Interactions of Cyclodextrin Dimers with Adamantyl-Containing LCST Copolymers [J]. Acta Chimica Sinica, 2012, 70(08): 1013-1020.
[14]	Jiang Jinqiang, Chen Xin, Yin Ming, Wang Zhouping, Liu Xiaoya, Chen Mingqing. Design and Synthesis of α-Cyclodextrin Modified Coumarin [J]. Acta Chimica Sinica, 2012, 0(05): 525-529 .
[15]	DUAN Wen-Sheng, LIU Bin, SUN Zhan-Guo, YANG Bin-Sheng. Synthesis, Characterization and Interaction with β-Cyclodextrin of Complex [Cr(4-Me-SA)(en)₂]Cl•0.5CH₃OH [J]. Acta Chimica Sinica, 2011, 69(15): 1789-1794.

烷氧基苯基卟啉与环糊精的超分子体系研究

Supramolecular System of Alkoxyphenylporphyrin with Cyclodextrins

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments