Theory of cyclic voltammetric reversible wave on oblate  hemispheroid ultramicroelectrode and its verification

Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (6): 570-577. Previous Articles Next Articles

Original Articles

超微半扁球电极上循环扫描可逆波理论及其验证

刁国旺;李亮;张祖训

南京大学化学系.南京(210008)

发布日期:1997-06-15

Theory of cyclic voltammetric reversible wave on oblate hemispheroid ultramicroelectrode and its verification

Diao Guowang;Li Liang;Zhang Zuxun

Nanjing Univ, Dept Chem.Nanjing(210008)

Published:1997-06-15

Abstract

The theory of cyclic voltammetric revresible wave on an oblate hemispheroid ultramicroelectrode has been described in this paper. The behaviours of curent-potential curve at different p and g have been discussed in detail. In order to verify the theory, the experiments were carried out on different mercury hemispheoid microelectrode with TCBQ-TBAP-acetonitrile system. The experimental results agreed with the theoretical ones.

Key words: MICROELECTRODE, CYCLOVOLTAMGRAPH, ACETONITRILE, CHLORANIL

CLC Number:

O646

Cite this article

Diao Guowang;Li Liang;Zhang Zuxun. Theory of cyclic voltammetric reversible wave on oblate hemispheroid ultramicroelectrode and its verification[J]. Acta Chimica Sinica, 1997, 55(6): 570-577.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Liu Qingyun, Zhao Xianghu, Li Jialu, Cao Song. Synthesis of Cyanated Difluorostyrene Derivatives via S_N2' Cyanomethylation of α-(Trifluoromethyl)styrenes with Acetonitrile [J]. Acta Chim. Sinica, 2018, 76(12): 945-950.
[2]	Jia Fengyan, Wang Wenwen, Liu Zhenbo, Yin Jungang, Liu Yongming. Extraction and Detection of Pyrethroids Pesticides in Fish Using Acetonitrile-Salt-H₂O System Coupled with Gas Chromatography [J]. Acta Chimica Sinica, 2012, 0(04): 485-491.
[3]	YIN Chuan-Qi, LIU Jun, BAI Zheng-Wu. Synthesis of a Water-Soluble Ruthenium Hydroxide Complex and Its Role in Catalytic Hydration of Acetonitrile [J]. Acta Chimica Sinica, 2011, 69(17): 2021-2025.
[4]	DENG Meng, WANG Mang, CHEN Hong-Zheng. Electrochemically Synthesized Polypyrrole Coatings and Their Effect on Electrical Properties of Neural Microelectrode [J]. Acta Chimica Sinica, 2011, 69(04): 477-482.
[5]	LIN Hai, SHENG Min-Qi, ZHONG Qing-Dong, ZHOU Qiong-Yu, WANG Yi, NIU Xiao-Bo. Effect of Nd^3＋ on Corrosion Electrochemical Behavior of Copper in 3.5% NaCl Solution by Using Microelectrode Array [J]. Acta Chimica Sinica, 2010, 68(12): 1153-1160.
[6]	XUAN Xiao-Peng; WANG Jian-Ji*; ZHAO Pei-Zheng; ZHAO Yang. Solvation of Lithium Ion in N,N-Dimethylformamide-based Mixtures [J]. Acta Chimica Sinica, 2007, 65(22): 2510-2514.
[7]	LAI Zu-Liang; WU Pei-Yi*. Probing Weak Interactions of Acetonitrile-Water-Sodium Perchlorate Mixtures Using Two Dimensional (2D) Correlation Infrared Spectroscopy [J]. Acta Chimica Sinica, 2006, 64(23): 2357-2364.
[8]	NIE Li, ZHANG Xuan, WU Fang-Ying, JIANG Yun-Bao. Anion Recognition by N-Benzamido-N’-phenylthioureas in Aqueous-Organic Binary Solvents [J]. Acta Chimica Sinica, 2004, 62(4): 369-372.
[9]	GU Ren-Ao, JIANG Yun, SUN Yu-Hua. Study on Surface Enhanced Raman Spectroscopy of DMSO and Imidazole at Silver Electrode in Acetonitrile Solution [J]. Acta Chimica Sinica, 2004, 62(23): 2352-2354.
[10]	Gu Jiashan;Chu Baobao;Zhou Xingfu;Shen Guangxia. Heterogeneous Electrocatalytic Reduction of Maleic Acid on Nanocrystalline TiO_2 Film Modified Ti Electrode [J]. Acta Chimica Sinica, 2003, 61(9): 1405-1409.
[11]	Sun Min;Xin Hao;Zhang Yongan;Wang Kezhi;Jin Linpei;Huang Chunhui. Synthesis, Characterization and Photoelectric Properties of a Novel Carbazole-containing Re(Ⅰ)Complex [J]. Acta Chimica Sinica, 2003, 61(8): 1323-1325.
[12]	Wang Jingping;Wei Meilin;Niu Jingyang. A Novel 1D Zigzag Chain Polyoxometallate-based Coordination Polymer ［｛La(DMSO)_6(H_2O)}·(PMo_(12)O_(40))·H_2O］_n: Synthesis, Crystal Structure and Characterization [J]. Acta Chimica Sinica, 2003, 61(8): 1276-1280.
[13]	Li Chunxiang;Li Jin;Xiao Langtao;Shen Guoli;Yu Ruqin. Amperometric Immunosensor Based on Mercapto Carboxylic Acid Self- assembled Monolayer for Phytohormone Indoleacetic Acid Assay [J]. Acta Chimica Sinica, 2003, 61(5): 790-794.
[14]	Wang Nanping;Zhang Qiping;Zhang Yuehua;Chen Hongyuan. Inclusion of Neurotransmitters in β-Cyclodextrin and Their Structures [J]. Acta Chimica Sinica, 2003, 61(4): 597-602.
[15]	Dong Sheying;Zheng Jianbin;Gao Hong. Investigation on Electrochemical Behavior of 3'-Daidzein Sulfonic Sodium and Its Application [J]. Acta Chimica Sinica, 2003, 61(4): 487-494.

超微半扁球电极上循环扫描可逆波理论及其验证

Theory of cyclic voltammetric reversible wave on oblate hemispheroid ultramicroelectrode and its verification

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments