Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (9): 887-892. Previous Articles     Next Articles

Original Articles

从(-)-α-蒎烯合成(IR,3R)-(+)-反式菊酸甲酯

刘铸晋;陆仁荣;顾禹归   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1987-09-15

The synthesis of methyl-(+)-(1R,3R)-trans-chrysanthemate from (-)-\a\-pinene

LIU ZHUJIN;LU RENRONG;GU YUGUI   

  • Published:1987-09-15

Me (+)-(1R,3R)-trans-chrysanthemate was synthesized from (-)-a-pinene, through a fourteen-step sequence with preservation of the 5R-chirality of the starting material (i.e. 3-C of the target mol.). The yield of each step proved reasonably high with an overall yield of 10.8%.

Key words: CYCLOPROPANE CARBOXYLIC ACID P, PROPENE P, PINENE, TURPENTINE, CHRYSANTHEMATE

CLC Number: