Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (7): 674-678. Previous Articles     Next Articles

Original Articles

1,1'-[四甲基二硅撑]二环戊二烯基二氯化钛的合成与结构

王瑛;徐善生;周秀中;王如骥;姚心侃   

  1. 南开大学化学系;南开大学测试计算中心
  • 发布日期:1988-07-15

Synthesis and structure of 1,1'-(tetramethyldisilandiyl)-dicyclopentadienyl titanium dichloride

WANG YING;XU SHANSHENG;ZHOU XIUZHONG;WANG RUJI;YAO XINKAN   

  • Published:1988-07-15

The title compound was obtained from the reaction of 1,2-dichlorotetramethyldisilane with cyclopentadienylsodium, BuLi, and TiCl4 in series in one pot. Its structure was established by elemental anal., 1H NMR, UV, mass spectroscopy, and confirmed by x-ray diffraction. The crystal is monoclinic.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, CRYSTAL STRUCTURE DETERMINATION, SODIUM COMPOUNDS, MOLECULAR STRUCTURE, X-RAY DIFFRACTION ANALYSIS, CYCLOPENTADIENE, PROTON MAGNETIC RESONANCE SPECTROMETRY, BUTYLLITHIUM, METALLOCENES, TITANIUM COMPLEX

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