Studies on the rare earth coordination compounds IV: Preparation and properties of the complexes of rare earth with 4-acetyl-bispyrazolone BPMPPD and 1,10-phenanthroline

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (9): 911-913. Previous Articles Next Articles

Original Articles

稀土配合物的研究 IV: 稀土元素与4-酰代双吡唑啉酮BPMPPD及1,10-二氮杂菲三元配合物的合成和性质的研究

杨鲁勤;杨汝栋

兰州大学化学系

发布日期:1989-09-15

Studies on the rare earth coordination compounds IV: Preparation and properties of the complexes of rare earth with 4-acetyl-bispyrazolone BPMPPD and 1,10-phenanthroline

YANG LUQIN;YANG RUDONG

Published:1989-09-15

Abstract

RE2A3L2.H2O [RE = Y, La, Pr, Nd, Sm-Lu; H2A = 1,5-bis(1'-phenyl-3'-methyl-5'-pyrazolon-4'-yl)-1,5-pentanedione; L = 1,10-phenanthroline, n = 4 for Y, La; n = 2 for other Re] were synthesized and characterized by elemental analyses and ligand analyses. The IR, UV-visible and, fluorescence spectra and DTA-TG curves of these complexes were recorded and discussed. The fluoroscence quantum yield of Sm, Tb complexes were measured.

Key words: PYRAZOLONE P, TERNARY COMPLEX, RARE EARTH METAL COMPLEX, RARE ELEMENT, ACYL COMPOUND, PHENANTHROLINE, QUANTUM EFFICIENCY, BETA DIKETONES, SOLID COMPLEX

CLC Number:

O611.662

Cite this article

YANG LUQIN;YANG RUDONG. Studies on the rare earth coordination compounds IV: Preparation and properties of the complexes of rare earth with 4-acetyl-bispyrazolone BPMPPD and 1,10-phenanthroline[J]. Acta Chimica Sinica, 1989, 47(9): 911-913.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Hongtao Cao, Pengfei Hou, Qing Cao, Yanang Li, Shasha Wang, Linghai Xie. Exciplex Emission and Property Investigation Based on Cyano-substituted 9-Phenylfluorene Derivative [J]. Acta Chimica Sinica, 2022, 80(11): 1476-1484.
[2]	Ma Mingshuo, Zou Luyi, Li Yan, Ren Aimin, Ding Xiaoli. Theoretical Studies on Photophysical Properties of Isomeric Iridium(Ⅲ) Complexes Ir(ppy)₂(acac) Containing Dimesitylboron Moiety [J]. Acta Chim. Sinica, 2016, 74(9): 764-772.
[3]	Wang Fangfang, Tao Youtian, Huang Wei. Recent Progress of Host Materials for Highly Efficient Blue Phosphorescent OLEDs [J]. Acta Chimica Sinica, 2015, 73(1): 9-22.
[4]	Shi Qinghua, Peng Qian, Sun Shaorui, Shuai Zhigang. Vibration Correlation Function Investigation on the Phosphorescence Quantum Efficiency and Spectrum for Blue Phosphorescent Ir(III) Complex [J]. Acta Chimica Sinica, 2013, 71(06): 884-891.
[5]	Tang Lanlan, Qi Zhengjian, Hong Manxin, Li Nan, Shen Wei, Yang Fan, Ji Xin, Hu Aijiang. Comparison Study of Oxygen Quenching of Ru(II) Phenanthroline Complexes with Different Functional Groups [J]. Acta Chimica Sinica, 2012, 70(9): 1081-1087.
[6]	Qiu Yixiang, Wang Shuguang. Theoretical Investigations on Tris(pentamethylcyclopentadienyl) Rare Earth Metal Complexes (C₅Me₅)₃Ln (Ln=Sc, Y, La) [J]. Acta Chimica Sinica, 2012, 70(18): 1930-1938.
[7]	Jia Juan, Luo Kaijun, Chen Yanfang, Zhao Baijing, Li Maowei. Synthesis and Photoelectric Property of Bis-Cyclometalated Iridium Complexes with 3-Acetyl Camphor as the Ancillary Ligand [J]. Acta Chimica Sinica, 2012, 70(08): 1028-1034.
[8]	Yang Shuping, Han Lijun, Pan Yan, Wu Zhenming, He Xinran, Chen Lijuan. Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi₂(PPA)₆?(Phen)₂] with Phenylacetic Acid and 1,10-Phenanthroline [J]. Acta Chimica Sinica, 2012, 0(04): 519-524.
[9]	FENG Xiao-Qiang, LI Xiao-Fang, YANG Sheng, FU Guo-Qing. Synthesis and Interaction of Cinnamic Acid-1,10-phenanthroline- La(III) Complexes with Bovine Serum Albumins [J]. Acta Chimica Sinica, 2011, 69(16): 1946-1950.
[10]	SONG Yu-Min, LIU Zhe, WANG Kun-Jie, LUAN Ni-Na. Interaction of the Ternary Complexes with Anticoagulant Property of Iron, Copper with Human Serum Albumin [J]. Acta Chimica Sinica, 2010, 68(21): 2191-2198.
[11]	. Synthesis and Properties of Metal 1,10-Phenanthroline Complexes Bridged by Tetrathiafulvalene Tetrathiolate [J]. Acta Chimica Sinica, 2009, 67(13): 1469-1474.
[12]	. Synthese and Anticoagulant Action of Rare Earth Ternary Complexes with Cysteine and Citrate [J]. Acta Chimica Sinica, 2009, 67(10): 1042-1046.
[13]	FAN Su-Hua; YANG Wei-Chun^1,2; WANG Ke-Zhi*^,1. Synthesis, Characterization and Acid-base Properties of a Carbazol- containing Mixed Ligand Ruthenium(II) Complex [J]. Acta Chimica Sinica, 2008, 66(6): 690-696.
[14]	. One-step Synthesis and Optical Properties of PbS Quantum Dots [J]. Acta Chimica Sinica, 2008, 66(16): 1869-1872.
[15]	HU, Xue-Lei ^*,a,b CHEN, Zhong ^a QIU, Lia LIU, Bo^b ZHAO, Yuan-Di ^b PAN, Zhi-Quan ^a LUO, Qin-Hui ^c . Synthesis, Crystal Structure and Luminescent Property of a Europium Nitrate Ternary Complex with a Diphenol Macrocyclic Ligand [J]. Acta Chimica Sinica, 2008, 66(12): 1446-1450.

稀土配合物的研究 IV: 稀土元素与4-酰代双吡唑啉酮BPMPPD及1,10-二氮杂菲三元配合物的合成和性质的研究

Studies on the rare earth coordination compounds IV: Preparation and properties of the complexes of rare earth with 4-acetyl-bispyrazolone BPMPPD and 1,10-phenanthroline

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments