Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (8): 1520-1523. Previous Articles     Next Articles

超强酸性室温离子液体反应介质中烷烃羰化研究

乔焜;邓友全   

  1. 中国科学院兰州化学物理研究所生态与绿色化学研究发展中心,兰州(730000)
  • 发布日期:2002-08-15

The First Example of Alkane Carbonylation in Superacidic Chloroaluminate Ionic Liquids

Qiao Kun;Deng Youquan   

  1. Centre for Ecological and Green Chemistry, Lanzhou Institute of Chemistry, Lanzhou Institute of Chemical Physics, CHinese Academy of Sciences,Lanzhou(730000)
  • Published:2002-08-15

Carbonylation of 2,2,4-trimethylpentane with CO was first time investigated in superacidic chloroaluminate ionic liquids consisting of AlCl_3 and 1-alkyl pyridium or 1-methyl-3-alkyl imidazolium halide quaternary ammonium salts. The products are ketones. A possible reaction route was proposed.

Key words: CARBONYLATION;ALKANE;SUPERACID;GLYOXALINE P;QUATERNARY AMMONIUM COMPOUNDS, CARBON MONOXIDE;KETONE

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