Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (1): 40-46. Previous Articles     Next Articles

Original Articles

硝酸银及其产物银对六角相液晶流变性影响

王红霞;张高勇   

  1. 武汉大学化学与分子科学学院,武汉(430072)
  • 发布日期:2003-01-15

Effect of AgNo_3 and As-produced Ag on Rheological Properties of Hexagonal Liquid Crystal

Wang Hongxia;Zhang Gaoyong   

  1. College of Chemistry and Molecular Science, Wuhan University,Wuhan (430072)
  • Published:2003-01-15

The effect of AgNO_3 and as-produced Ag on phase zone and viscoelastic properties of hexagonal liquid crystal was investigated by using polarized light microscope and RS-75 rheosress. AgNO_3 and as- produced Ag can make hexagonal phase region shrink slightly. The results of stress sweep show that the critical stresses decrease for pure hexagonal phase and are related to the applied frequency for samples adjacent to hexagonal phase zone. The frequency sweep shows that the relaxation time becomes long and the viscoelastic exponents decrease as results of the aggregation and connection of as-produced Ag on EO chains from the surface of micelles. The results of creep are accordance with ones of oscillation experiment and quantify viscoelastic composition, which explained by the springdashpot model and spacial configuration and interaction in hexagonal phase.

Key words: SILVER NITRATE, HEXAGON, LIQUID CRYSTAL, PHASE STRUCTURE, RHEOLOGICAL PROPERTY, NANOPHASE MATERIALS, SILVER, POLARIZING MICROSCOPES

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