1^H、7^Li、23^Na、133^Cs NMR study on the complex properties of azamacrocyclic ether-bislactones and amine-bislactam

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (2): 164-169. Previous Articles Next Articles

Original Articles

1^H、7^Li、23^Na、133^Cs NMR研究含氮大环醚双内酯和大环胺双内酰胺的配合性能

张安将;王树梅;秦圣英

中国科学院成都有机化学研究所;四川大学化学系

发布日期:1991-02-15

1^H、7^Li、23^Na、133^Cs NMR study on the complex properties of azamacrocyclic ether-bislactones and amine-bislactam

ZHANG ANJIANG;WANG SHUMEI;QIN SHENGYING

Published:1991-02-15

Abstract

The complexations of N,N-dicarboxymethyl macrocyclic ether-bislactones and amine-bislactam, N-tosyl-macrocyclic ether-bislactones, and 4'-(dansylamin)benzo-18-crown-6 with Li+, Na+, K+, Cs+, Cd2+ and Pb2+ ions were studied by 1H, 7Li, 23Na, 133Cs NMR and the formation constants of complexes were calculated by nonlinear-least-squares program KINFIT. Also a 133Cs NMR technique was developed for the measurement of formation constants of crown ether complexes that uses competition of a crown ether and I- for a given Cs+.

Key words: LACTONES, NMR SPECTROMETRY, NITROGEN HETEROCYCLICS, CROWN ETHER COMPOUNDS, PROTON MAGNETIC RESONANCE SPECTROMETRY, LITHIUM ISOTOPES, CYCLIC ETHER, LEAST SQUARE METHODS, COMPLEX CONSTANT, SODIUM ISOTOPES

CLC Number:

O611.662

Cite this article

ZHANG ANJIANG;WANG SHUMEI;QIN SHENGYING. 1^H、7^Li、23^Na、133^Cs NMR study on the complex properties of azamacrocyclic ether-bislactones and amine-bislactam[J]. Acta Chimica Sinica, 1991, 49(2): 164-169.

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1^H、7^Li、23^Na、133^Cs NMR研究含氮大环醚双内酯和大环胺双内酰胺的配合性能

1^H、7^Li、23^Na、133^Cs NMR study on the complex properties of azamacrocyclic ether-bislactones and amine-bislactam

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