Synthesis of β-triarylgermanium and β-tris(2-thiophene) germanium substituted propionic acids

Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (3): 288-293. Previous Articles Next Articles

Original Articles

β-三芳基锗和β-三(α-噻吩基)锗取代丙酸的合成

孙丽娟;张金菊;白明章

南开大学元素有机化学研究所

发布日期:1992-03-15

Synthesis of β-triarylgermanium and β-tris(2-thiophene) germanium substituted propionic acids

SUN LIJUAN;ZHANG JINJU;BAI MINGZHANG

Published:1992-03-15

Abstract

Six b-(triarylgermanium)-substituted propionic acids, e.g., Ph3GeCH2CH2CO2H, and 8 b-(tri-2-thienylgermanium)- substituted propionic acids, e.g., I, were synthesized from Cl3GeCHR1CHR2CO2H (R1 = aryl, H; R2 = Me, H). All these compounds were characterized by elemental anal., IR and 1H NMR. Eleven new b-(N-arylamide)propylgermanium sesquioxides, e.g., (GeCH2CHMeCONHPh)nO1.5n were also synthesized and characterized by elemental anal. and IR.

Key words: CHEMICAL COMPOSITION, METHYLACETIC ACID P, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, PROTON MAGNETIC RESONANCE SPECTROMETRY, STRUCTURAL ANALYSIS, THIOPHENE P, ORGANO GERMANIUM

CLC Number:

O627

Cite this article

SUN LIJUAN;ZHANG JINJU;BAI MINGZHANG. Synthesis of β-triarylgermanium and β-tris(2-thiophene) germanium substituted propionic acids[J]. Acta Chimica Sinica, 1992, 50(3): 288-293.

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β-三芳基锗和β-三(α-噻吩基)锗取代丙酸的合成

Synthesis of β-triarylgermanium and β-tris(2-thiophene) germanium substituted propionic acids

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