Acta Chimica Sinica ›› 1995, Vol. 53 ›› Issue (6): 595-602. Previous Articles     Next Articles

Original Articles

含氮杂环化合物的固相光化学

孟继本;王文广;杜大明;熊国祥;王永梅   

  1. 南开大学化学系
  • 发布日期:1995-06-15

Solid state photochemistry of nitrogenous heteraromatic compounds

MENG JIBEN;WANG WENAN;DU DAMING;XIONG GUOXIANG;WANG YONGMEI   

  • Published:1995-06-15

Photochemical reaction of nitrogenous heteraromatic compounds with uracil aldehyde, aromatic aldehydes and ketones, fused polycyclic aromatic hydrocarbons in solid state were investigated and were distinct from that solution. The structures of 19 new compounds synthesized were determined by IR, ^1H NMR, MS and elemental analysis. Theses mixed crystals have been characterized by the powder X-ray diffraction spetra and differential scanning calorimetry curve. The mixed crystals of indole with naphthalene and carbazole with anthracene were found to form molecular compounds. The reaction mechanism was postulated.

Key words: PHOTOCHEMISTRY, MIXED CRYSTALS, HETEROCYCLIC COMPOUNDS, SOLID PHASES, NITROGEN-CONTAINING ORGANIC COMPOUNDS, AROMATIC ALDEHYDE

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