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Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (10): 1641-1645. Previous Articles Next Articles
Original Articles
孙小玲;李兴亚;蒋锡夔;傅伟敏
发布日期:
Sun Xiaoling;Li Xingya;Jiang Xikui;Fu Wimin
Published:
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Enamines react spontaneously with CF_3CXYZ (X, Y, Z = Cl, Br) without UV irradiation or initiators,and form Z-isomers of β-CF_3 substituted a , β-unsaturated ketones as major products in 50% yields. The reaction may proceed via radical intermediates which is initiated by electron transfer.
Key words: ENAMINES, ETHANE P, HALOHYDROCARBON, CHARGE TRANSFER REACTION, FREE RADICAL REACTION
CLC Number:
O621
Sun Xiaoling;Li Xingya;Jiang Xikui;Fu Wimin. Novel Reactions of Enamines with Perhaloethanes: A Facile Route to β-CF_3 Substituted α, β-Unsaturated Ketones[J]. Acta Chimica Sinica, 2003, 61(10): 1641-1645.
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